| Identification | Back Directory | [Name]
meso-Tetra(4-carboxyphenyl)porphine | [CAS]
14609-54-2 | [Synonyms]
Mtcpp
Aids006254
Aids-006254
RARECHEM AS SA 0048
NICKEL IONOPHORE II
tetrakis(benzoic acid)
tetracarboxyphenylporphine
TETRACARBOXYPHENYLPORPHYRIN
Tetrakis(carboxphenyl)porphyrin
TETRAKIS(4-CARBOXYPHENYL)PORPHINE
Tetrakis(4-carboxyphenyl)porphyrin
MESO-TETRA(4-CARBOXYPHENYL)PORPHINE
4,4,4,4-(POrphine-5,10,15,20-tetrayl)
meso-tetrakis(4-carboxyphenyl)porphine
meso-Tetrakis(4-carboxyphenyl)porphyrin
meso-Tetra(4-carboxyphenyl)porphine,98%
In - tetrakis (4-carboxyphenyl) porphine
5,10,15,20-TETRA(4-CARBOXYPHENYL)PORPHYRIN
TCPP [=Tetrakis(4-carboxyphenyl)porphyrin]
(porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid)
5,10,15,20-Tetrakis(4-carboxyphenyl)-21H,23H-porphine
5,10,15,20-TETRAKIS-(4-CARBOXYPHENYL)-21,23H-PORPHYRIN
MESO-TETRAPHENYLPORPHINE-4,4',4'',4'''-TETRACARBOXYLIC ACID
4,4',4'',4'''-(PORPHINE-5,10,15,20-TETRAYL)TETRAKIS(BENZOIC ACID)
4,4',4'',4'''-(21H,23H-Porphyrin-5,10,15,20-tetryl)tetrakis(benzoic acid)
4,4',4'',4'''-(21H,23H-PORPHINE-5,10,15,20-TETRAYL)TETRAKIS(BENZOIC ACID)
4,4',4'',4'''-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid) Dye content 75 %
Meso-tetra(4-carboxyphenyl)porphine
4,4,4,4-(POrphine-5,10,15,20-tetrayl)tetrakis(benzoic acid)
meso-Tetraphenylporphine-4,4μ,4,4μ-tetracarboxylic acid, 4,4μ,4μμ,4μμμ-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid)
TCPP [=Tetrakis(4-carboxyphenyl)porphine] [Ultra-high sensitive spectrophotometric reagent for Cu, Cd] [For the simultaneous determination of metals by HPLC]
MESO-TETRA(4-CARBOXYPHENYL)PORPHINE 98% ULTRA-HIGH SENSITIVE SPECTROPHOTOMETRIC REAGENT FOR CU CD AND USE FOR THE SIMULTANEOUS DETERMINATION OF METALS BY HPLC
TCPP [=Tetrakis(4-carboxyphenyl)porphyrin] [Ultra-high sensitive spectrophotometric reagent for Cu, Cd] [For the simultaneous determination of metals by HPLC] | [Molecular Formula]
C48H30N4O8 | [MDL Number]
MFCD00064860 | [MOL File]
14609-54-2.mol | [Molecular Weight]
790.77 |
| Chemical Properties | Back Directory | [Melting point ]
>300 °C | [density ]
1.462±0.06 g/cm3(Predicted) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [form ]
Powder | [color ]
purple | [Appearance]
Purple to Black Solid | [λmax]
411 nm | [InChIKey]
HHDUMDVQUCBCEY-LWQDQPMZSA-N | [SMILES]
C1(C2=CC=C(C=C2)C(O)=O)=C2N=C(C(C3=CC=C(C=C3)C(O)=O)=C3NC(=C(C4=CC=C(C=C4)C(O)=O)C4=NC(=C(C5=CC=C(C=C5)C(O)=O)C5NC1=CC=5)C=C4)C=C3)C=C2 |c:24,t:10,27,41| |
| Hazard Information | Back Directory | [Description]
5,10,15,20-(tetra-4-carboxyphenyl)porphyrin is a sensor for Ni2+. | [Uses]
meso-Tetra(4-carboxyphenyl)porphine can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and chemical production processes. | [General Description]
| [Synthesis]
General procedures for the synthesis of porphyrins 1-5A mixture of the appropriate aromatic aldehyde (0.72 mmol) andpyrrole (0.72 mmol) in DMF (15 mL) was placed into a 50 mL threeneckedflask. The mixture was flushed with nitrogen gas for a coupleof minutes and then heated to 100 C for 10 min. P-toluene sulphonicacid (0.72 mmol, dissolved in DMF) was then added to the reactionmixture. The colorless mixture turned red over the next couple of minutesthen heated at 150 C for 1 h. The reaction mixture was thencooled and poured over ice with stirring for 15 min the residue wascollected, dried under vacuum and purified by column chromatographyusing chloroform/hexane (1.5/1) as eluent). |
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