| Identification | Back Directory | [Name]
2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE | [CAS]
14812-59-0 | [Synonyms]
2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxa-phosphol
2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE
1,3,2-Dioxaphospholane, 2-chloro-4,4,5,5-tetramethyl-
2-Chloro-4,4,5,5-tetraMethyl-1,3,2-dioxaphospholane 95% | [Molecular Formula]
C6H12ClO2P | [MDL Number]
MFCD00274239 | [MOL File]
14812-59-0.mol | [Molecular Weight]
182.59 |
| Chemical Properties | Back Directory | [Boiling point ]
81.5-82 °C13 mm Hg(lit.) | [density ]
1.149 g/mL at 25 °C(lit.) | [refractive index ]
n20/D 1.471(lit.) | [Fp ]
>230 °F | [InChI]
InChI=1S/C6H12ClO2P/c1-5(2)6(3,4)9-10(7)8-5/h1-4H3 | [InChIKey]
WGPCXYWWBFBNSS-UHFFFAOYSA-N | [SMILES]
O1C(C)(C)C(C)(C)OP1Cl |
| Hazard Information | Back Directory | [Description]
2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane(14812-59-0) is an organic reagent commonly used in chemical and experimental research as a reagent for the phosphorylation of alcohols and heteroatoms for the formation of glycosyl donors and ligands, and in analytical studies of derivatised lignin samples. It is also used as a catalyst in CuO/TiO2 catalysed lignin oxidation studies.
| [Chemical Properties]
2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane is an organic reagent in the physical state of a solid. Molecular weight: 182.59, Density: 1.149 g/cm3, Boiling point: 81.5-82° C (lit.) at 13 mmHg, Flash point: 113 °C, Refractive index: n20/D 1.471 (lit.), Store at 10°C-25°C, keep dry, under inert gas nitrogen. | [Uses]
2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane (TMDP,14812-59-0) can be used:
- As a reagent for the phosphitylation of alcohols and heteroatomic nucleophiles, resulting in the formation of useful glycosyl donors and ligands.
- As a phosphitylation reagent to derivatize lignin samples for 31P NMR analysis.
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
|
| Company Name: |
Shureli Biopharma Co.,Ltd Gold
|
| Telephone: |
0871-68355600 18787766125 |
| Website: |
www.chemicalbook.com/showsupplierproductslist1143315/0.htm |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Rhawn Reagent
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| Telephone: |
400-400-1332688 18019345275 |
| Website: |
http://www.rhawn.cn |
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