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14973-89-8

14973-89-8 Structure

14973-89-8 Structure
IdentificationBack Directory
[Name]

BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
[CAS]

14973-89-8
[Synonyms]

orange crystal
Einecs 239-050-5
BROMOTRIS(TRIPHENYLP
99.95%(metalsbasis),Rh10.1%min
Tris(triphenylphosphine)bromide
bromotris(triphenylphosphine)rhodium
BROMO-TRIS-(TRIPHENYLPHOSPHINO)RHODIUM
BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
rhodium(I) tris(triphenylphosphine) bromide
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) BROMI DE
Bromotris(triphenylphosphine)rhodium(I), 99.95% (metals basis)
Bromotris(Triphenylphosphine)Rhodium(I) (Metals Basis), Rh 10.1% Min
Bromotris(triphenylphosphine)rhodium(I), 99.95% (metals basis), Rh 10.1% min
[EINECS(EC#)]

239-050-5
[Molecular Formula]

C54H45BrP3Rh
[MDL Number]

MFCD00009828
[MOL File]

14973-89-8.mol
[Molecular Weight]

969.67
Chemical PropertiesBack Directory
[Appearance]

orange crystals
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[solubility ]

Soluble in chlorinated solvents
[form ]

Crystalline
[Sensitive ]

Air sensitive
[Exposure limits]

ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
Hazard InformationBack Directory
[Chemical Properties]

orange crystals
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22
[Safety Statements ]

36
Questions And AnswerBack Directory
[Reaction]

  1. Rhodium-catalyzed regio- and stereoselective addition of diphenylphosphine oxide to alkynes.
  2. Rhodium- catalyzed hydrophosphinylation.
Reactions of 14973-89-8
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