ChemicalBook--->CAS DataBase List--->14976-80-8

14976-80-8

14976-80-8 Structure

14976-80-8 Structure
IdentificationBack Directory
[Name]

CHROMIUM(II) ACETATE MONOHYDRATE DIMER
[CAS]

14976-80-8
[Synonyms]

chromous acetate monohydrate dimer
CHROMIUM(II) ACETATE MONOHYDRATE DIMER
Chromium(II) acetate,dimer monohydrate
Acetic Acid Chromium(II) Salt Monohydrate
Acetic Acid Chromium(II) Salt Monohydrate DISCONTINUED
[Molecular Formula]

C8H14Cr2O9
[MDL Number]

MFCD00167309
[MOL File]

14976-80-8.mol
[Molecular Weight]

358.18
Chemical PropertiesBack Directory
[solubility ]

slightly sol cold water; readily sol hot water; sol in and reacts with most acids; slightly sol alcohol; practically insol ether.
[form ]

powder
[Appearance]

deep red powder or monoclinic crystals
[InChI]

1S/4C2H4O2.2Cr.H2O/c4*1-2(3)4;;;/h4*1H3,(H,3,4);;;1H2/q;;;;2*+2;/p-4
[InChIKey]

FZQQGORSNJYWHB-UHFFFAOYSA-J
[SMILES]

O.CC(=O)O[Cr]OC(C)=O.CC(=O)O[Cr]OC(C)=O
Safety DataBack Directory
[WGK Germany ]

2
[RTECS ]

AG3000000
[Storage Class]

13 - Non Combustible Solids
Hazard InformationBack Directory
[Uses]

Used as capable of reducing reactive carbon-halogen bonds (e.g. allylic, benzylic, α-halo carbonyl); bromohydrins and epoxides; used in the conversion of ketoximes to ketones in the presence of acid- and base-sensitive functional groups).
[reaction suitability]

reagent type: catalyst
core: chromium
[storage]

Easily oxidized, especially when moist, to chromium(III) acetate. It can be stored for several months in a stoppered vial under carbon dioxide.
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