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150-50-5

150-50-5 Structure

150-50-5 Structure
IdentificationBack Directory
[Name]

MERPHOS
[CAS]

150-50-5
[Synonyms]

Folex
Folen
MERPHOS
FOLEX(R)
folex6ec
easyoff-d
NSC 27720
folex (tm)
Easy off-D
deleafdefoliant
Deleaf defoliant
DELEAF DEFOLLIANT
Tributylthiofosfin
tributyltrithiophosphite
Tris(butylthio)phosphine
tris(butylthio)phosphane
butylphosphorotrithioite
Tributyl trithiophosphite
Merphos @100 μg/mL in MeOH
tris(butylsulfanyl)phosphane
TRIBUTYLPHOSPHORO-TRITHIOITE
Merphos @1000 μg/mL in Hexane
s,s,s-tributyltrithiophosphite
S,S,S-Tributyl trithiophosphite
s,s,s-tributylphosphorotrithioite
butylphosphorotrithioite[(bus)3p]
Merphos 100 μg/mL in Acetonitrile
S,S,S-Tributyl phosphorotrithioite
Butyl phosphorotrithioite ((bus)3p)
phosphorotrithiousacid,tributylester
S,S,S-TRI-N-BUTYLPHOSPHOROTRITHIOITE
Trithiophosphorous acid tributyl ester
Phosphorotrithious acid, tributyl ester
phosphorotrithiousacid,s,s,s-tributylester
Tributylphosphorotrithioite 1g [150-50-5]
Phosphorotrithious acid, S,S,S-tributyl ester
Tributylphosphoro-trithioite 250mg [150-50-5]
[EINECS(EC#)]

205-761-4
[Molecular Formula]

C12H27PS3
[MDL Number]

MFCD00128008
[MOL File]

150-50-5.mol
[Molecular Weight]

298.51
Chemical PropertiesBack Directory
[Melting point ]

100°C
[Boiling point ]

115-134 °C(Press: 0.08 Torr)
[density ]

1.0200
[solubility ]

Chloroform (Slightly), Dichloromethane (Slightly), Diethyl Ether (Slightly)
[form ]

Liquid
[Stability:]

Air Sensitive, Hygroscopic, Moisture Sensitive
[EPA Substance Registry System]

Merphos (150-50-5)
Hazard InformationBack Directory
[Chemical Properties]

Nearly colorless liquid. Insoluble in water; soluble in a variety of organic solvents.
[Uses]

Organophosphate pesticide used in the agriculture industry
[General Description]

Emulsifiable oil.
[Reactivity Profile]

Organothiophosphates, such as MERPHOS, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
[Hazard]

Cholinesterase inhibitor.
[Environmental Fate]

Merphos is adsorbed strongly to soil and oxidized to S,S,S-tributyl phosphorotrithioate (DEF). The Koc estimated for merphos is theoretically 62 000; accordingly, merphos would be immobile in soil.
In water, merphos will be oxidized to DEF. The fact that merphos is expected to adsorb strongly to particulate matter in the water column, apparently did not impede its oxidation.
In the atmosphere, merphos will exist as an aerosol and be removed by gravitational settling and readily oxidized to DEF. Vapor-phase merphos will react with photochemically produced hydroxyl radicals, with an estimated half-life of 4.9 h.
Safety DataBack Directory
[RIDADR ]

3278
[TSCA ]

TSCA listed
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[Safety Profile]

Poison by intraperitoneal route. Moderately toxic by ingestion and skin contact. A cholinesterase inhibitor. Combustible when exposed to heat or flame. Can react vigorously with oxidzing materials. When heated to decomposition it emits highly toxic fumes of POx and SOx. Used as a defoliant. See also PARATHION.
[Hazardous Substances Data]

150-50-5(Hazardous Substances Data)
[Toxicity]

guinea pig,LD50,oral,850mg/kg (850mg/kg),Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 27(8), Pg. 97, 1962.
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