ChemicalBook--->CAS DataBase List--->1516140-99-0

1516140-99-0

1516140-99-0 Structure

1516140-99-0 Structure
IdentificationBack Directory
[Name]

Sodium oxane-4-sulfinate
[CAS]

1516140-99-0
[Synonyms]

Baran THPS-Na Reagent
Sodium oxane-4-sulfinate
Sodium tetrahydropyransulfinate
[Molecular Formula]

C5H11NaO3S
[MDL Number]

MFCD24113367
[MOL File]

1516140-99-0.mol
[Molecular Weight]

174.19
Chemical PropertiesBack Directory
[storage temp. ]

RT, stored under nitrogen, away from moisture
[form ]

solid
[Appearance]

White to off-white Solid
[InChI]

1S/C5H10O3S.Na/c6-9(7)5-1-3-8-4-2-5;/h5H,1-4H2,(H,6,7);/q;+1/p-1
[InChIKey]

JIOKFXIXTDFEIS-UHFFFAOYSA-M
[SMILES]

O=S(C1CCOCC1)[O-].[Na+]
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.
[reaction suitability]

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
Spectrum DetailBack Directory
[Spectrum Detail]

Sodium oxane-4-sulfinate(1516140-99-0)1HNMR
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