| Identification | Back Directory | [Name]
3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline | [CAS]
151657-37-3 | [Synonyms]
Li-Quinoline Ligand
2,5-Dimethyl-3,4-dihydro-2H-pyrano[2,3-b]quinoline
3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline
2H-Pyrano[2,3-b]quinoline, 3,4-dihydro-2,5-dimethyl- | [Molecular Formula]
C14H15NO | [MDL Number]
MFCD28053559 | [MOL File]
151657-37-3.mol | [Molecular Weight]
213.27 |
| Chemical Properties | Back Directory | [Melting point ]
143-147°C | [Boiling point ]
367.9±21.0 °C(Predicted) | [density ]
1.117±0.06 g/cm3(Predicted) | [form ]
solid | [pka]
4.26±0.40(Predicted) | [InChI]
1S/C14H15NO/c1-9-7-8-12-10(2)11-5-3-4-6-13(11)15-14(12)16-9/h3-6,9H,7-8H2,1-2H3 | [InChIKey]
ZENOEMLZOZWVRD-UHFFFAOYSA-N | [SMILES]
CC1=C2C(OC(C)CC2)=NC3=C1C=CC=C3 |
| Hazard Information | Back Directory | [Uses]
Ligand can be used in the presence of Pd(TFA)2 (Aldrich 299685) to promote C-H activation of β-Aryl-α-amino acids. This product has shown to be optimal with a 2:1 ratio of Ligand:Pd Source for several examples reported by the Yu group. | [reaction suitability]
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation |
|
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|