153724-93-7

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153724-93-7 Structure

Identification	Back Directory
[Name] 3-Chloropropenyl-1-boronic acid pinacol ester
[CAS] 153724-93-7
[Synonyms] 3-Chlorophenyl-1-boronic Acid Pinacol Ester 3-Chloropropenyl-1-boronic acid pinacol ester (E)-3-Chloro-1-propene-1-boronic Acid Pinacol Ester trans-2-Chloromethylvinylboronic acid pinacol ester 97% 2-[(E)-3-chloroprop-1-enyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (E)-2-(3-Chloro-1-propenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (E)-2-(3-Chloroprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-[(E)-3-chloroprop-1-en-1-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-[(1E)-3-chloroprop-1-en-1-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 1,3,2-Dioxaborolane, 2-[(1E)-3-chloro-1-propen-1-yl]-4,4,5,5-tetramethyl- 3-Chloropropenyl-1-boronic acid pinacol ester,2-(3-Chloro-propenyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane
[Molecular Formula] C9H16BClO2
[MDL Number] MFCD09260446
[MOL File] 153724-93-7.mol
[Molecular Weight] 202.49

Chemical Properties	Back Directory
[density ] 1.028 g/mL at 25 °C
[refractive index ] n20/D1.4603
[Fp ] 100℃
[storage temp. ] Storage temp. 2-8°C
[Appearance] Colorless to light yellow Liquid
[Boiling point ] 57-62°C/0.3-0.4 mmHg

Safety Data	Back Directory
[WGK Germany ] 3

[Uses]

trans-2-Chloromethylvinylboronic acid pinacol ester is a common reactant of Suzuki coupling reaction. It can be used to prepare:

Readout reagent that helps in providing qualitative and quantitative readouts in enzyme biomarker detection assays.
Boronated enynes, which on Au(I) catalyzed cycloisomerization yield various dienyl boronates.
α-Methyl-substituted boronates for the allylation of ketones to yield homoallylic tertiary alcohols.

Spectrum Detail	Back Directory
[Spectrum Detail] 3-Chloropropenyl-1-boronic acid pinacol ester(153724-93-7)¹HNMR

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