ChemicalBook--->CAS DataBase List--->153766-81-5

153766-81-5

153766-81-5 Structure

153766-81-5 Structure
IdentificationBack Directory
[Name]

POTASSIUM PHENYLTRIFLUOROBORATE
[CAS]

153766-81-5
[Synonyms]

Potassium phenylfluoroborate
Potassium Thienylfluoroborate
POTASSIUM PHENYLTRIFLUOROBORATE
potassiuM trifluoro(phenyl)borate
Potassium phenyltrifluoroborate 98%
Potassium phenyltrifluoroborate,95%
phenyltrifluoroboric acid potassium salt
benzenetrifluoroboric acid potassium salt
Benzenetrifluoroboric acid potassium salt~Phenyltrifluoroboric acid potassium salt
[EINECS(EC#)]

-0
[Molecular Formula]

C6H5BF3K
[MDL Number]

MFCD01318172
[MOL File]

153766-81-5.mol
[Molecular Weight]

184.01
Chemical PropertiesBack Directory
[Appearance]

White powder
[Melting point ]

300°C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[color ]

White
[Water Solubility ]

Soluble in water.
[BRN ]

7782070
[InChI]

1S/C6H5BF3.K/c8-7(9,10)6-4-2-1-3-5-6;/h1-5H;/q-1;+1
[InChIKey]

DVAFPKUGAUFBTJ-UHFFFAOYSA-N
[SMILES]

[K+].F[B-](F)(F)c1ccccc1
Hazard InformationBack Directory
[Chemical Properties]

White powder
[Uses]

Aryltrifluoroborate salts are more nucleophilic than the corresponding arylboronic acids and undergo ligand-free Pd-catalyzed cross-coupling reactions with arenediazonium tetrafluoroborates to give good yields of biaryls. Suzuki Cross-Coupling are conducted using organotrifluoroborates as a potent boronic acid surrogates. In the presence of Dicarbonyl-(2,4-pentanedionato)-rhodium(I)-, 39295, K aryl- and alkenyltrifluoroborates add to aldehydes and enones to give secondary alcohols and saturated ketones, respectively.
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HS Code ]

29319090
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Spectrum DetailBack Directory
[Spectrum Detail]

POTASSIUM PHENYLTRIFLUOROBORATE(153766-81-5)1HNMR
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