| Identification | Back Directory | [Name]
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE | [CAS]
158923-09-2 | [Synonyms]
JOSIPHOS SL-J004-1
OSIPHOS SL-J004-1
(R)1[(1S)2(di-C-hex
(R)1 (1S)2(DI-C-HEXYLPHOSPHINO)FERROCEN&
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ET
(R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-diphenylphosphin
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
(R,R)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine >=97%
(S)-(-)-l-[(S)-2-( Dicyclohexylphosphino)ferroceny1] ethyldicyclohexylphosphino
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine,min.97%
(r,r)-1-(dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene (acc to cas)
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO) FERROCENYL]ETHYLDIPHENYLPHOSPHINE, MIN. 97%
Josiphos SL-J004-1, (1R)-1-(Dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS) | [Molecular Formula]
C36H44FeP2 10* | [MDL Number]
MFCD00800280 | [MOL File]
158923-09-2.mol | [Molecular Weight]
594.53 |
| Chemical Properties | Back Directory | [alpha ]
-100° ±5° (c 0.5, CHCl3) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [color ]
orange | [InChIKey]
AWOOIDCKLIQAJV-KHZPMNTOSA-N | [SMILES]
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(C3CCCCC3)C4CCCCC4)P(c5ccccc5)c6ccccc6 |
| Hazard Information | Back Directory | [Chemical Properties]
Red crystal | [Uses]
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand:
- To prepare iridium metal complex (IrIJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.
- In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.
| [General Description]
sold in collaboration with Solvias AG |
| Questions and Answers (Q&A) | Back Directory | [Reactions]
1. Ligand for asymmetric hydroformylation reactions
2. Ligand for asymmetric intramolecular amide arylation
3. Ligand for enantioselective 1,6-conjugate addition of Grignard reagents to linear dienolates
4. Ligand for enantioselective synthesis of vicinal dialkyl arrays
5. Ligand for asymmetric conjugate addition of Grignard reagents to chromones
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