ChemicalBook--->CAS DataBase List--->1602922-03-1

1602922-03-1

1602922-03-1 Structure

1602922-03-1 Structure
IdentificationBack Directory
[Name]

-
[CAS]

1602922-03-1
[Synonyms]

Methanesulfonato[4,6-bis(diphenylphosphino)phenoxazine](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Methanesulfonato[4,6-bis(diphenylphosphino)phenoxazine](2'-amino-1,1'-biphenyl-2-yl)palladium(II),[NiXantphos Palladacycle Gen. 3]
[Molecular Formula]

C49H40N2O4P2PdS
[MDL Number]

MFCD28144626
[MOL File]

1602922-03-1.mol
[Molecular Weight]

921.3
Questions And AnswerBack Directory
[Uses]

[4,6-bis(diphenylphosphine)phenoxazine](2-amino-1,1-biphenyl-3-yl)palladium(II) methanesulfonic acid is mainly used as a catalyst in organic synthesis.
[Reaction]

  1. Synthesis of diarylmethylamines via palladium-catalyzed arylation of 1,1,3-triaryl-2-azaallyl anions.
  2. Catalyst used in the generation of diaryl sulfoxides from aryl benzyl sulfoxides and aryl chlorides.
Reactions of 1602922-03-1
Chemical PropertiesBack Directory
[storage temp. ]

2-8°C, protect from light, stored under nitrogen
[form ]

solid
[color ]

light green yellow
[InChIKey]

RKPGNKWNXMCYQX-UHFFFAOYSA-M
[SMILES]

O=S(O[Pd]C1=CC=CC=C1C2=CC=CC=C2N)(C)=O.C3(P(C4=CC=CC=C4)C5=CC=CC=C5)=C(OC(C(P(C6=CC=CC=C6)C7=CC=CC=C7)=CC=C8)=C8N9)C9=CC=C3
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H335-H319
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
[WGK Germany ]

WGK 3
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
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