| Identification | Back Directory | [Name]
Baran TFCS-Na Reagent | [CAS]
1622292-60-7 | [Synonyms]
Baran TFCS-Na Reagent
Sodium 1-(trifluoromethyl)cyclopropanesulfinate
1-(Trifluoromethyl)cyclopropane-1-sulfinate (sodium)
1-(trifluoromethyl)cyclopropane-1-sulfinic acid sodium | [Molecular Formula]
C4H6F3NaO2S | [MDL Number]
MFCD28124332 | [MOL File]
1622292-60-7.mol | [Molecular Weight]
198.13 |
| Chemical Properties | Back Directory | [Melting point ]
287-292 °C | [form ]
solid | [InChI]
InChI=1S/C4H5F3O2S.Na.H/c5-4(6,7)3(1-2-3)10(8)9;;/h1-2H2,(H,8,9);; | [InChIKey]
FDZSYKYMWJRYNH-UHFFFAOYSA-N | [SMILES]
C(C1(CC1)S(O)=O)(F)(F)F.[NaH] |
| Hazard Information | Back Directory | [Uses]
Sodium 1-?(Trifluoromethyl)?cyclopropanesulfinat?e acts as a reagent for the preparation of sulfinate salts from carboxylic acids and mercaptopyridine N-oxide via Barton reaction and ruthenium-catalyzed oxidation for C-H functionalization of heterocycles. | [reaction suitability]
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation |
|
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|