| Identification | Back Directory | [Name]
- | [CAS]
1702744-45-3 | [Synonyms]
Nicl(O-Tolyl)(Tmeda)
chloro(2-methylphenyl)(N,N,N`,N`-tetramethyl-1,2-ethylenediamine)nickel
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
Chloro(2-methylphenyl)(N,N,N'',N''-tetramethyl-1,2-ethylenediamine)nickel(II)
CHLORO(2-METHYLPHENYL)(N,N,N',N'-TETRAMETHYL-1,2-ETHYLENEDIAMINE)NICKEL(II),99%(CONTAINSABOUT5%O-CHLOROTOLUENE)NICL(O-TOLYL)(TMEDA)
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 10% o-chlorotoluene) NiCl(o-tolyl)(TMEDA) | [Molecular Formula]
C13H23ClN2Ni | [MDL Number]
MFCD29037017 | [MOL File]
1702744-45-3.mol | [Molecular Weight]
301.482 |
| Chemical Properties | Back Directory | [form ]
Powder | [color ]
dark-orange | [Sensitive ]
air sensitive | [InChI]
1S/C7H7.C6H16N2.ClH.Ni/c1-7-5-3-2-4-6-7;1-7(2)5-6-8(3)4;;/h2-5H,1H3;5-6H2,1-4H3;1H;/q;;;+1/p-1 | [InChIKey]
NMLMESVZRUMFAE-UHFFFAOYSA-M | [SMILES]
CC1=CC=CC=C1[Ni]Cl.CN(C)CCN(C)C |
| Questions And Answer | Back Directory | [Reaction]
- Air-Stable Nickel precatalyst for cross-coupling
- Precatalyst allowing various ligands to be used (monoand bidendate phosphines, diimines and NHCs)
|
| Hazard Information | Back Directory | [Uses]
Effective precatalyst for a variety of nickel-catalyzed transformations, including Suzuki-Miyaura, Buchwald-Hartwig and other cyclizations and oxidative couplings. | [reaction suitability]
core: nickel
reaction type: Cross Couplings
reagent type: catalyst |
|
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