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172418-32-5

172418-32-5 Structure

172418-32-5 Structure
IdentificationBack Directory
[Name]

TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)
[CAS]

172418-32-5
[Synonyms]

cataCXium? C
trans-Di(µ
Herrmanns Catalyst
trans-Di(?acS46-1989
Herrmann′s palladacycle
Herrmann-Beller catalyst
Herrmann-Beller palladacycle
trans-Bis(acetato)bis[2-[bis(2
DiacetatobisodiotolylphosphinobenzyldipalladiumII
-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium (II)
trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II)
TRANS-DI(-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM(II)
TRANS-DI-MU-ACETATOBIS[2-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM(II)
TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)
TRANS-DI-U(M)-ACETATOBIS[2-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM(II)
TRANS-DI-MU(M)-ACETATOBIS[2-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM(II)
TRANS-DI-(MY-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)
trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium
trans-Di-μ-acetatobis[2-(di-o-tolylphosphino)benzyl]dipalladium(II), 94%
trans-di-aeu(m)-acetatobis[2-(di-o-tolylphosphino)benzyl]dipalladium(ii)
trans-Di-^m-acetatobis[2-(di-o-tolylphosphino)benzyl]dipalladium(II), 94%
trans-Di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II), 97+%
trans-Di-μu(m)-acetatobis2-(di-o-tolylphosphino)benzylüdipalladium(II), 98%
trans-Bis(acetato)bis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium(II)
trans-Bis(acetato)bis[2-[bis(2-Methylphenyl)phosphiNA]benzyl]dipalladiuM(II)
trans-Di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladiuM(II) [cataCXiuM C]
trans-Di(mu-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II),97+%[cataCXiumC]
cataCXium(R) C, trans-Di(μ-acetato)bis[o-(di-o-tolyl-phosphino)benzyl]dipalladium(II)
trans-Di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium (II), 97+% [cataCXium C]
trans-Di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II), 97+% [cataCXium(R) C]
[Molecular Formula]

2C23H23O2PPd
[MDL Number]

MFCD01631283
[MOL File]

172418-32-5.mol
[Molecular Weight]

937.65
Chemical PropertiesBack Directory
[Melting point ]

230°C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

crystal
[color ]

yellow
[InChI]

1S/2C21H20P.2C2H4O2.2Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;2*1-2(3)4;;/h2*4-15H,1H2,2-3H3;2*1H3,(H,3,4);;/q;;;;2*+1/p-2
[InChIKey]

DUHUARWWBNTVDI-UHFFFAOYSA-L
[SMILES]

CC(=O)O[Pd]Cc1ccccc1P(c2ccccc2C)c3ccccc3C.CC(=O)O[Pd]Cc4ccccc4P(c5ccccc5C)c6ccccc6C
Hazard InformationBack Directory
[Chemical Properties]

Yellow powder
[Uses]

Homogeneous catalyst in carbon-carbon bond forming reactions such as the Heck and Suzuki reactions.
[General Description]

sold in collaboration with Solvias AG
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
reagent type: ligand
reaction type: Asymmetric synthesis
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P301+P312-P302+P352-P304+P340-P305+P351+P338
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[HS Code ]

28439000
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

Heck olefination of haloarenes. Reactions of 172418-32-5
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