| Identification | Back Directory | [Name]
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) | [CAS]
174810-09-4 | [Synonyms]
(R,R)-TROST LIGAND(NAPHTHYL)
(R,R)-DACH-naphthyl Trost ligand
(R,R)-DACH-naphthyl Trost ligand 95%
N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide)
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94%
1-NaphthalenecarboxaMide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-
N,N'-(1R,2R)-Cyclohexane-1,2-diylbis[2-(diphenylphosphanyl)naphthalene-1-carboxamide]
(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(R,R)-DACH-Naphthyl Trost Ligand
(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (R,R)-DACH-Naphthyl Trost Ligand
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(R,R)-DACH-NaphthylTrostLigand | [Molecular Formula]
C52H44N2O2P2 | [MDL Number]
MFCD02684551 | [MOL File]
174810-09-4.mol | [Molecular Weight]
790.87 |
| Chemical Properties | Back Directory | [Appearance]
white to off-white powder | [Melting point ]
224-231 °C | [alpha ]
69o (C=1 IN METHANOL) | [form ]
Powder | [pka]
13.43±0.40(Predicted) | [color ]
off-white | [Optical Rotation]
[α]20/D +69.0°, c = 1 in methanol | [InChIKey]
VXFKMKXTPXVEMU-AWSIMMLFSA-N | [SMILES]
C1(NC(C2=C3C(C=CC=C3)=CC=C2P(C2=CC=CC=C2)C2=CC=CC=C2)=O)CCCCC1NC(C1=C2C(C=CC=C2)=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1)=O | [CAS DataBase Reference]
174810-09-4 |
| Questions And Answer | Back Directory | [Reactions]
The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and fluorides nucleophiles.
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