| Identification | Back Directory | [Name]
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) | [CAS]
174813-82-2 | [Synonyms]
[(R,R)-TsDPEN-Ru(Mesitylene)Cl]
Chloro[(1R,2R)-N-(p-toluenesulfonyl)-1,2-diphenylethanediamine](mesitylene)ruthenium(II)
Chloro[[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido](mesitylene)ruthenium(II)
[R-(R*,R*)]-[N-(2-Amino-1,2-diphenylethyl)-4-methylbenzenesulfonamidato-N,N']chloro[(1,2,3,4,6-η)-1,3,5-trimethylbenzene]ruthenium
Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(Mesitylene)rutheniuM(II),90% RuCl[(R,R)-Tsdpen(Mesitylene)
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(
mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) | [Molecular Formula]
C30H30ClN2O3RuS- | [MDL Number]
MFCD12545951 | [MOL File]
174813-82-2.mol | [Molecular Weight]
635.159 |
| Chemical Properties | Back Directory | [Melting point ]
241-249°C | [storage temp. ]
2-8°C | [form ]
Powder | [color ]
orange | [Sensitive ]
air sensitive | [InChIKey]
HTPIQYBAGIDYTK-IDJGTMRTNA-L | [SMILES]
CC1=CC(C)=CC(C)=C1.[Ru-]1(Cl)NC(=O)C2=CC=C(S1(=O)=O)C([C@@H](C1=CC=CC=C1)[C@@H](N)C1=CC=CC=C1)=C2 |&1:22,29,r| |
| Hazard Information | Back Directory | [Uses]
RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:
- (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
- Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.
|
|
|