| Identification | Back Directory | [Name]
ZIRCONIUM(IV) ACETYLACETONATE | [CAS]
17501-44-9 | [Synonyms]
ac150
X 1044
ZC 150
ZR 181
orgatixzc150
nasemuzirconium
acetyl-zirconiuacetonate
2,4-pentanedione,zrderiv.
ZIRCONIUM ACETYLACETONATE
ZirconiuM(IV) acetylaceton
Zirconium(Ⅳ) acetylacetonate
ZIRCONIUM 2,4-PENTANEDIONATE
ZIRCONIUM(IV) ACETYLACETONATE
tetraacetylacetonatezirconium
Zinconium (IV) acetylacetonate
Zirconium tetraacetylacetonate
ZIRCONIUM(IV) 2,4-PENTANEDIONATE
ACETYLACETONE ZIRCONIUM(IV) SALT
2,4-pentanedione,zirconiumcomplex
Tetrakis(acetylacetonyl)zirconium
ZirconiuM(IV) acetylacetonate 98%
Tetrakis(acetylacetonato)zirconium
2,4-Pentanedione, zirconium complex
Zirconium tetrakis(acetylacetonate)
ACETYLACETONE, ZIRCONIUM DERIVATIVE
Zirconium(IV)acetylacetonate,min.98%
"Zirconium 2,4-pentanedionate/ 98+%"
Zirconium, tetrakis(acetylacetonato)-
tetrakis(2,4-pentanedionato)-zirconiu
Tetrakis(2,4-pentanedionato)zirconium
TETRAKIS(ACETYLACETONATO)ZIRCONIUM(IV)
Zirconium tetrakis(2,4-pentanedionate)
Zirconium(IV) acetylacetonate, min. 98%
ZIRCONIUM(IV) ACETYLACETONATE FOR SYNTHE
Zirconium, tetrakis(pentan-2,4-dionato)-
Zirconium, tetrakis(2,4-pentanedionato)-
TETRAKIS(2,4-PENTANEDIONATO)ZIRCONIUM(IV)
2,4-PENTANEDIONE, ZIRCONIUM(IV) DERIVATIVE
tetrakis(2,4-pentanedionato-o,o’)-zirconiu
tetrakis(2,4-pentanedionato-O,o’)zirconium
tetrakis(pentane-2,4-dionato-O,O')zirconium
zirconium,tetrakis(2,4-pentanedionato-O,o’)-
Tetrakis(acetylacetonato)-zirconium(IV)(β-form)
Zirconium acetylacetonate
Acetylacetone Zirconium(IV) Salt
Acetylacetone Zirconium(IV) Salt
Zirconium(IV) Acetylacetonate
4-pentanedionato-o,o’)-tetrakis((sa-8-11’’11’’1’1’’’1’1’’’)-zirconiu
tetrakis(2,4-pentanedionato-kappao,kappao’)-zirconiu(sa-8-11’’11’’1’1’’’
tetrakis(2,4-pentanedionato-O,O’)-,(SA-8-11’’11’’1’1’’’1’1’’’)-Zirconium
Zirconium, tetrakis(2,4-pentanedionato-O,O')-, (SA-8-11''11''1'1'''1'1''')-
Zirconium, tetrakis(2,4-pentanedionato-.kappa.O,.kappa.O)-, (SA-8-11111111)-
2,4-Pentanedione zirconium(IV) derivative
Tetrakis(2,4-pentanedionato)zirconium(IV)
Tetrakis(acetylacetonato)zirconium(IV)~Tetrakis(2,4-pentanedionato)zirconium(IV)~Zirconium(IV)2,4-pentanedionate
2,4-Pentanedione zirconium(IV) derivative, Tetrakis(2,4-pentanedionato)zirconium(IV), Zirconium(IV) 2,4-pentanedionate | [EINECS(EC#)]
241-510-5 | [Molecular Formula]
C20H28O8Zr | [MDL Number]
MFCD00000036 | [MOL File]
17501-44-9.mol | [Molecular Weight]
487.66 |
| Chemical Properties | Back Directory | [Melting point ]
191-195 °C
| [bulk density]
500kg/m3 | [density ]
1.42g/cm3 at 20℃ | [vapor pressure ]
0-0Pa at 20-25℃ | [storage temp. ]
Store below +30°C. | [solubility ]
14g/l | [form ]
Powder | [color ]
white | [PH]
7.2 (4.5g/l, H2O, 20℃) | [Water Solubility ]
Soluble in water. | [BRN ]
4160373 | [Exposure limits]
ACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3 | [InChI]
1S/4C5H8O2.Zr/c4*1-4(6)3-5(2)7;/h4*3,6H,1-2H3;/q;;;;+4/p-4/b4*4-3-; | [InChIKey]
FPFOSIXCIBGKOH-MTOQALJVSA-J | [SMILES]
CC(=O)\C=C(\C)O[Zr](O\C(C)=C/C(C)=O)(O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O | [LogP]
0.12-0.2 at 20℃ and pH7.1 | [Surface tension]
67.28mN/m at 1g/L and 20℃ | [EPA Substance Registry System]
Zirconium, tetrakis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SA-8-11''11''1'1'''1'1''')- (17501-44-9) |
| Hazard Information | Back Directory | [Chemical Properties]
Light yellow powder | [Uses]
Zirconium(IV) 2,4-pentanedionate is used as a cross-linking agent for oxygen-containing polymers. It is used as a catalyst in organic synthesis for the nitration of o-nitrotoluene using a dinitrogen pentoxide to get 2,4-dinitrotoluenes and 2,6-dinitrotoluenes. | [Application]
Starting material for zirconium metallomesogens: zirconium tetrakis-β-diketonate liquid crystals. | [reaction suitability]
core: zirconium
reagent type: catalyst | [Purification Methods]
The zirconium complex crystallises from hot 95% EtOH (m 190-191o) or pet ether and sublimes in vacuo at 140o with slight decomposition. The decahydrate effloresces in air and dehydrates in a 0.1mm vacuum. Its solubility in 1L at 20o is 30g in CS2, 47g in CCl4, 44g in ethylene dibromide, 56g in acetonylacetone and 200g in *C6H6. [Young & Arch Inorg Synth II 122 1964, Beilstein 1 H 782, 1 II 835, 1 III 3121, 1 IV 3672.] |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
22-40-36/37/38-20/21/22-63 | [Safety Statements ]
22-24/25-36/37-26-7 | [WGK Germany ]
3
| [RTECS ]
ZH9280000
| [TSCA ]
Yes | [HS Code ]
29141900 | [Storage Class]
4.1B - Flammable solid hazardous materials | [Hazard Classifications]
Acute Tox. 4 Oral
Flam. Sol. 1 | [Safety Profile]
Poison by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating fumes. Used as a cross-linking agent for oxygen-containing polymers. See also ZIRCONIUM COMPOUNDS | [Toxicity]
LD50 orally in Rabbit: 719 mg/kg |
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