ChemicalBook--->CAS DataBase List--->1779569-01-5

1779569-01-5

1779569-01-5 Structure

1779569-01-5 Structure
IdentificationBack Directory
[Name]

Chloro(1-t-butylindenyl)palladium(II) dimer, 98%
[CAS]

1779569-01-5
[Synonyms]

Chloro(1-t-butylindenyl)palladium(II) dimer, 98%
[Molecular Formula]

C26H30Cl2Pd2
[MOL File]

1779569-01-5.mol
[Molecular Weight]

622.23
Chemical PropertiesBack Directory
[Melting point ]

166 °C
[form ]

Powder
[color ]

brown
[SMILES]

CC(C)(C)[C@H]1[C@H]2[C@H](CCCC2)CC1.C[Pd]Cl.C[Pd]Cl.CC(C)(C)c3ccc4c3cccC4
Safety DataBack Directory
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P280-P305+P351+P338-P304+P340-P405-P501A
[Risk Statements ]

36/37/38
[Safety Statements ]

26-37-60
[WGK Germany ]

WGK 3
[TSCA ]

No
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

Starting material used to prepare monomeric chloro(t-butylindenyl)(ligand)palladium complexes. Reactions of 1779569-01-5
Hazard InformationBack Directory
[Uses]

The following palladium dimer is a precatalyst scaffold for cross-coupling reactions originally reported by the Hazari research group. When used with an selected ligand, the precatalyst exhibits superior activity over a wide array of cross-coupling reactions and under a variety of conditions.
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
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