| Identification | Back Directory | [Name]
SODIUM TRIMETHYLSILANOLATE | [CAS]
18027-10-6 | [Synonyms]
Sodium trimethyL
Sodiooxytrimethylsilane
Trimethyl(sodiooxy)silane
(Sodiooxy)trimethylsilane
SODIUM TRIMETHYLSILANOLATE
trimethyl-silanosodiumsalt
TRIMETHYLSILANOL, SODIUM SALT
1.0Msolutionindichloromethane
SodiuM triMethylsilanolate 95%
SodiuM odiuM triMethylsilanolate
Silanol, trimethyl-, sodium salt
Sodium trimethylsilanolate solution
Sodium trimethylsilanolate,Trimethylsilanol sodium salt
Sodium trimethylsilanolate, 1M solution in THF, AcroSeal
SodiuM triMethylsilanolate, 1.0 M solution in THF, J&KSeal
SodiuM triMethylsilanolate, 1.0 M solution in THF, HySeal Spc
SODIUM TRIMETHYLSILANOLATE, 1.0M SOLUTIO N IN DICHLOROMETHANE
SODIUM TRIMETHYLSILANOLATE, 1.0M SOLUTIO N IN TETRAHYDROFURAN
Sodium trimethylsilanolate, 1M solution in dichloromethane, AcroSeal | [EINECS(EC#)]
241-939-8 | [Molecular Formula]
C3H9NaOSi | [MDL Number]
MFCD00013926 | [MOL File]
18027-10-6.mol | [Molecular Weight]
112.18 |
| Chemical Properties | Back Directory | [Melting point ]
230 °C (dec.)(lit.)
| [density ]
1.283 g/mL at 25 °C
| [Fp ]
−2 °F
| [solubility ]
DMSO (Sparingly) | [form ]
Solid | [color ]
White to Off-White | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [BRN ]
3912148 | [InChI]
InChI=1S/C3H9OSi.Na/c1-5(2,3)4;/h1-3H3;/q-1;+1 | [InChIKey]
HSNUIYJWTSJUMS-UHFFFAOYSA-N | [SMILES]
[Si]([O-])(C)(C)C.[Na+] | [CAS DataBase Reference]
18027-10-6 | [EPA Substance Registry System]
Silanol, trimethyl-, sodium salt (18027-10-6) |
| Hazard Information | Back Directory | [Uses]
Sodium trimethylsilanolate is used as a catalyst in the: - Synthesis of the rhodium silonate complex.
- Silylation of methylphenylsilane with tert-butyldimethylsilanol to synthesize trisiloxanes.
| [Purification Methods]
It is very soluble in Et2O and *C6H6 but moderately soluble in pet ether. It is purified by sublimation at 130-150o in a high vacuum. [Hyde et al. J Am Chem Soc 75 5615 1953, Tatlock & Rochow J Org Chem 17 1555 1952, Beilstein 4 III 1856.] |
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