| Identification | Back Directory | [Name]
1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE | [CAS]
18422-53-2 | [Synonyms]
D-EPOXONE
D-EPOXONE(R)
D-Epoxone(rg
-[1,4]dioxolan]-7-one
(3aR,6S,7aR)-2,2,5'
Shi’s epoxidation catalyst
shi epoxidation diketal catalyst
Shi Epoxidation Diketal Catalyst 98%
1,2:4,5-DI-O-ISOPROPYLIDENE-BETA- &
1 2:4 5-DI-O-ISOPROPYLIDENE-B-D-ERYTHRO&
1,2:4,5-di-O-isopropylidene-B-D-*erythro-2,3-hexo
di-O-isopropylidene-beta-D-erythro-2,3-hexodiulopyranose
-tetramethyl-tetrahydro-2H-spiro[[1,3]dioxolo[4,5-c]pyran-6,2'
4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE
1,2:4,5-DI-O-ISOPROPYLIDEN-BETA-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE
1,2:4,5-di-o-isopropylidene-á-d-erythro-2,3-hexodiulo-2,6-pyranose
1,2:4,5-di-o-isopropylidene-β-d-erythro-2,3-hexodiulo-2,6-pyranose
1,2:4,5-di-O-isopropylidene-β-D-erythro-hexo-2,3-diulo-2,6-pyranose
1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE
1,2:4,5-Bis-O-isopropylidene-beta-D-erythro-2,3-hexodiulo-2,6-pyranose
1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE USP/EP/BP
(3aR,4'R,7aR)-2,2,2',2'-tetramethyldihydrospiro[[1,3]dioxolo[4,5-c]pyran-6,4'-[1,3]dioxolan]-7(7aH)-one
(3a'R,4R,7a'R)-2,2,2',2'-tetramethyldihydrospiro[[1,3]dioxolane-4,6'-[1,3]dioxolo[4,5-c]pyran]-7'(4'H)-one
(3'aR,4S,7'aR)-2,2,2',2'-tetramethylspiro[1,3-dioxolane-4,6'-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran]-7'-one | [Molecular Formula]
C12H18O6 | [MDL Number]
MFCD00063383 | [MOL File]
18422-53-2.mol | [Molecular Weight]
258.27 |
| Chemical Properties | Back Directory | [Melting point ]
102-104 °C(lit.)
| [Boiling point ]
341.9±42.0 °C(Predicted) | [density ]
1.28±0.1 g/cm3(Predicted) | [storage temp. ]
2-8°C
| [solubility ]
Soluble in chloroform and methanol. | [form ]
Solid | [color ]
White to Pale Yellow | [Optical Rotation]
[α]20/D 120.9°, c = 1 in chloroform | [BRN ]
1319073 | [InChI]
InChI=1S/C12H18O6/c1-10(2)15-6-12(18-10)9(13)8-7(5-14-12)16-11(3,4)17-8/h7-8H,5-6H2,1-4H3 | [InChIKey]
IVWWFWFVSWOTLP-UHFFFAOYSA-N | [SMILES]
C12(COC(C)(C)O1)OCC1OC(C)(C)OC1C2=O |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302-H315-H319-H335 | [Precautionary statements ]
P261-P301+P312-P302+P352-P304+P340-P305+P351+P338 | [Safety Statements ]
22-24/25 | [WGK Germany ]
3
| [HS Code ]
29329990 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
White Solid | [Uses]
1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose is a chemical reagent used in the synthesis of Irciniastatin (A & B), cytotoxic secondary metabolites. Used in epoxidation reactions.
| [General Description]
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