ChemicalBook--->CAS DataBase List--->1848244-75-6

1848244-75-6

1848244-75-6 Structure

1848244-75-6 Structure
IdentificationBack Directory
[Name]

[2',4'-Bis(1,1-dimethylethyl)-6'-methoxy[1,1'-biphenyl]-2-yl]dicyclohexylphosphine
[CAS]

1848244-75-6
[Synonyms]

phosphino-2'-methoxy-4',6'-di-t-butyL
2-Dicyclohexylphosphino-2'-methoxy-4',6'-di-t-buty
2-Dicyclohexylphosphino-2′-methoxy-4′,6′-di-tert-butylbiphenyl
2-Dicyclohexylphosphino-2'-methoxy-4',6'-di-t-butyl-1,1'-biphenyl
2-Dicyclohexylphosphino-2'-methoxy-4',6'-di-t-butyl-1,1'-biphenyl, Vphos
2',4' -di-tert-butyl-6 '-methoxy-1,1' -biphenyl -2-dicyclohexylphosphine
Dicyclohexyl(2',4'-di-tert-butyl-6'-methoxy-[1,1'-biphenyl]-2-yl)phosphane
2-Dicyclohexylphosphino-2'-methoxy-4',6'-di-t-butyl-1,1'-biphenyl,min.98%VPhos
[2',4'-Bis(1,1-dimethylethyl)-6'-methoxy[1,1'-biphenyl]-2-yl]dicyclohexylphosphine
Phosphine, [2',4'-bis(1,1-dimethylethyl)-6'-methoxy[1,1'-biphenyl]-2-yl]dicyclohexyl-
[Molecular Formula]

C33H49OP
[MDL Number]

MFCD30184625
[MOL File]

1848244-75-6.mol
[Molecular Weight]

492.72
Chemical PropertiesBack Directory
[Melting point ]

113-118 °C
[Boiling point ]

561.5±50.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,Store in freezer, under -20°C
[form ]

solid
[color ]

white to off-white
[InChI]

1S/C33H49OP/c1-32(2,3)24-22-28(33(4,5)6)31(29(23-24)34-7)27-20-14-15-21-30(27)35(25-16-10-8-11-17-25)26-18-12-9-13-19-26/h14-15,20-23,25-26H,8-13,16-19H2,1-7H3
[InChIKey]

LYVFKWGKMKCNPE-UHFFFAOYSA-N
[SMILES]

P(C1=CC=CC=C1C1=C(OC)C=C(C(C)(C)C)C=C1C(C)(C)C)(C1CCCCC1)C1CCCCC1
Safety DataBack Directory
[WGK Germany ]

WGK 3
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Uses]

As the Pd G4 complex, this ligand from the Buchwald group offers best-in-class performance in the micellar aqueous Negishi coupling of heterocyclic alkyl bromides.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand
reaction type: click chemistry
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