| Identification | Back Directory | [Name]
9-(3-bromophenyl)carbazole | [CAS]
185112-61-2 | [Synonyms]
NBPC
N-(3-BroMophenyl)carbazole
9-(3-bromophenyl)carbazole
N-(3-BroMophenyl)-9H-carbazole
9-(3-Bromophenyl)carbazole >
9H-Carbazole, 9-(3-broMophenyl)-
N-(3-BroMophenyl)carbazole(N3BPC)
9-(3-bromophenyl)carbazole ISO 9001：2015 REACH
9-(3-broMophenyl)carbazole/
N-(3-BroMophenyl)carbazole
9-(3-BROMOPHENYL)CARBAZOLE; N-(3-BROMOPHENYL)CARBAZOLE; 9-(3-BROMOPHENYL)-9H-CARBAZOLE | [EINECS(EC#)]
807-965-4 | [Molecular Formula]
C18H12BrN | [MDL Number]
MFCD20486475 | [MOL File]
185112-61-2.mol | [Molecular Weight]
322 |
| Chemical Properties | Back Directory | [Melting point ]
69-70℃ | [Boiling point ]
463℃ | [density ]
1.39 | [Fp ]
234℃ | [storage temp. ]
Sealed in dry,Room Temperature | [form ]
powder to crystal | [color ]
White to Almost white | [InChI]
InChI=1S/C18H12BrN/c19-13-6-5-7-14(12-13)20-17-10-3-1-8-15(17)16-9-2-4-11-18(16)20/h1-12H | [InChIKey]
ZKGHGKNHPPZALY-UHFFFAOYSA-N | [SMILES]
N1(C2=CC=CC(Br)=C2)C2=C(C=CC=C2)C2=C1C=CC=C2 |
| Hazard Information | Back Directory | [Chemical Properties]
White solid | [Uses]
9-(3-bromophenyl)carbazole can be used to synthesize organic optoelectronic materials.
| [Hazard]
9-(3-bromophenyl)carbazole can cause skin irritation and serious eye irritation.
| [Synthesis]
1-bromo-3-iodobenzene, 2.02 mL (15.8mmol), copper (Cu) 2.29 g (36.0 mmol) of calcium carbonate and 4.98 g (36.0 mmol) of DMF in 30 mL insert heated at 130 It was stirred. After the completion of the reaction, it cooled to ambient temperature, diluted with ethyl acetate to a vacuum filter, and passed through a silica gel. The filtrate was concentrated under reduced pressure. Separating the product by silica gel column chromatography (ethyl acetate: n-hexane = 1: 20) to give 9-(3-bromophenyl)carbazole 3.80 g (98 per cent yield). | [References]
[1] Patent: KR101593182, 2016, B1. Location in patent: Paragraph 0427; 0430; 0438; 0439
[2] Patent: CN107686484, 2018, A. Location in patent: Paragraph 0123-0128
[3] Patent: KR101622443, 2016, B1. Location in patent: Paragraph 0109; 0110
[4] RSC Advances, 2015, vol. 5, # 64, p. 51512 - 51523
[5] Patent: WO2012/4765, 2012, A2. Location in patent: Page/Page column 73-74 |
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