| Identification | Back Directory | [Name]
(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL | [CAS]
185913-98-8 | [Synonyms]
(R)-CL-MEO-BIPHEP
(S)-CL-MEO-BIPHEP
min.(s)-cl-meo-biphep
(5,5'-Dichloro-6,6'-dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine)
(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5'-DICHLORO-6,6'-DIMETHOXY-1,1'-BIPHENYL
(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5'-DICHLORO-6,6'-DIMETHOXY-1,1'-BIPHENYL
(-)-5,5'-DICHLORO-2,2'-BIS(DIPHENYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL
(+)-5,5'-DICHLORO-2,2'-BIS(DIPHENYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL
(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
(r)-(-)-5,5'-dichloro-2,2'-bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
(S)-(-)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
(-)-(5,5'-DICHLORO-6,6'-DIMETHOXY-1,1'-BIPHENYL)-2,2'-DIYL-BIS(DIPHENYLPHOSPHINE)
(+)-(5,5'-DICHLORO-6,6'-DIMETHOXY-1,1'-BIPHENYL)-2,2'-DIYL-BIS(DIPHENYLPHOSPHINE)
(S)-(-)-5,5'-Dichloro-6,6'-diMethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl (S)-Cl-MeO-BIPHEP
(S)-(-)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl,min.95%(S)-Cl-MeO-BIPHEP | [Molecular Formula]
C38H30Cl2O2P2 | [MDL Number]
MFCD03426987 | [MOL File]
185913-98-8.mol | [Molecular Weight]
651.5 |
| Chemical Properties | Back Directory | [Melting point ]
176-180 °C
| [Boiling point ]
678.2±55.0 °C(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [color ]
yellow-white | [Optical Rotation]
[α]20/D 59.0±4°, c = 1% in chloroform | [InChIKey]
GCBRCSSVOVNEIX-UHFFFAOYSA-N | [SMILES]
COc1c(Cl)ccc(P(c2ccccc2)c3ccccc3)c1-c4c(OC)c(Cl)ccc4P(c5ccccc5)c6ccccc6 |
| Questions And Answer | Back Directory | [Reactions]
- Ligand used in the ruthenium catalyzed, enantioselective hydrogenation of alkenes, carbonyls,and imines.
- Ligand used in the rhodium-catalyzed cyclization of acetylenic aldehydes.
- Ligand used in the iridium-catalyzed hydrogenative coupling of alkynes to aromatic and aliphatic N-arylsulfonyl aldimines.
- Asymmetric Cu-catalyzed propargylic substitution with amines,4a and enamines.4b
- Catalytic desymmetrizing intramolecular Heck reaction.
- Assembly of 1,3-polyols.
- Pd-catalyzed diastereo/enantioselective allylic alkylations of ketone enolates.
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