| Identification | Back Directory | [Name]
phosphoric acid,2-naphthalenyl diphenyl ester | [CAS]
18872-49-6 | [Synonyms]
2-Naphthyl diphenyl phosphate
2-Naphthalenyl diphenyl ester
Naphthalen-2-yl diphenyl phosphate
2-Naphthyl diphenyl phosphate（PNDP）
phosphoric acid,2-naphthalenyl diphenyl ester
2-Naphthalenyl diphenyl ester in stock Factory | [Molecular Formula]
C22H17O4P | [MDL Number]
MFCD22380593 | [MOL File]
18872-49-6.mol | [Molecular Weight]
376.34 |
| Chemical Properties | Back Directory | [storage temp. ]
Inert atmosphere,Room Temperature | [InChI]
InChI=1S/C22H17O4P/c23-27(24-20-11-3-1-4-12-20,25-21-13-5-2-6-14-21)26-22-16-15-18-9-7-8-10-19(18)17-22/h1-17H | [InChIKey]
JSJUBNHZCFKUKY-UHFFFAOYSA-N | [SMILES]
P(OC1=CC=CC=C1)(OC1=CC=CC=C1)(OC1=CC=C2C(=C1)C=CC=C2)=O |
| Hazard Information | Back Directory | [Synthesis]
GENERAL METHOD: To a solution of dichloromethane (CH2Cl2, 0.2 M) containing the alcohol component (2-naphthol, 0.9 mmol), pyridine-N-oxide (0.045 mmol, 5 mol%) and Proton Sponge (1.8 mmol) was added the specified phosphoryl chloride (diphenyl chlorophosphate, 1.0 mmol). The reaction mixture was stirred at room temperature for a specified time before methanol (MeOH, 2 mL) was added. Subsequently, the reaction mixture was concentrated under vacuum. The crude product was purified by fast chromatography to afford the target product diphenyl phosphorodiphenyl-2-naphthyl ester. | [References]
[1] Synlett, 2015, vol. 26, # 7, p. 985 - 990
[2] Journal of the Chemical Society, 1951, p. 980,985 |
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Energy Chemical
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021-58432009 400-005-6266 |
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http://www.energy-chemical.com |
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