ChemicalBook--->CAS DataBase List--->19131-99-8

19131-99-8

19131-99-8 Structure

19131-99-8 Structure
IdentificationBack Directory
[Name]

(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE
[CAS]

19131-99-8
[Synonyms]

N-Methyl-1-phenylethanamine
(S)-N,α-Dimethylbenzylamine
N-Methyl-(S)-α-phenylethylamine
(S)-N-METHYL-1-PHENYLETHANAMINE
(S)-(-0-N,α-DIMETHYLBENZYLAMINE
(s)-(-)-n,α-dimethylbenzylamine
(S)-(-)-N,A-DIMETHYLBENZYLAMINE
S(-)-N-METHYL-1-PHENYLETHYLAMINE
(1S)-N-Methyl-1-phenylethanamine
(+)-Methyl-<1-phenyl-ethyl>-aMin
S-N,α-diMethyl-BenzeneMethanaMin
[(S)-1-(Methylamino)ethyl]benzene
(S)-N,α-Dimethylbenzenemethanamine
(S)-N-METHYL-ALPHA-PHENYLETHYLAMINE
(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE
(S)-(-)-N-METHYL A-METHYLBENZYLAMINE
(S)(-)-N-METHYL-ALPHA-PHENETHYLAMINE
[S,(-)]-N,α-Dimethylbenzenemethanamine
(S)-(-)-N,alpha-Dimethylbenzylamine 98%
Benzenemethanamine, N,.alpha.-dimethyl-
(S)-(-)-Nalpha-Dimethylbenzylamine, 99+%
Benzenemethanamine, N,α-dimethyl-, (αS)-
BenzeneMethanaMine, N,a-diMethyl-, (aS)-
(S)-(-)-alpha-Methyl-N-methylbenzylamine
(S)-N,α-Dimethylbenzenemethanamine,99%e.e.
[Molecular Formula]

C9H13N
[MDL Number]

MFCD00067113
[MOL File]

19131-99-8.mol
[Molecular Weight]

135.21
Chemical PropertiesBack Directory
[Melting point ]

116°C (estimate)
[alpha ]

-72o (C=2 IN CHLOROFORM)
[Boiling point ]

74-76 °C11 mm Hg(lit.)
[density ]

0.928 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.512(lit.)
[Fp ]

143 °F
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[form ]

clear liquid
[pka]

9.77±0.10(Predicted)
[color ]

Colorless to Almost colorless
[Optical Rotation]

[α]20/D 73±5°, c = 2 in chloroform
[BRN ]

1446867
[InChI]

1S/C9H13N/c1-8(10-2)9-6-4-3-5-7-9/h3-8,10H,1-2H3/t8-/m0/s1
[InChIKey]

RCSSHZGQHHEHPZ-QMMMGPOBSA-N
[SMILES]

CN[C@@H](C)c1ccccc1
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H302-H312-H314-H332
[Precautionary statements ]

P280-P305+P351+P338-P310
[Hazard Codes ]

C
[Risk Statements ]

20/21/22-34
[Safety Statements ]

26-36-45
[RIDADR ]

UN 2619 8/PG 2
[WGK Germany ]

3
[F ]

10-23
[HazardClass ]

IRRITANT
[HS Code ]

29214990
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Oral
Skin Corr. 1B
Hazard InformationBack Directory
[Uses]

Used to make asymmetric organometallic catalysts (e.g., for conjugate additions to enones).
[General Description]

(S)-(-)-N,a-Dimethylbenzylamine may be used along with benzaldehyde in the Mannich-type aminoalkylation of 2-naphthol to form 1-((S)-phenyl(((1′S)-1′-phenylethyl)methylamino)methyl)-2-naphthol. This optically active tertiary aminonaphthol can catalyze the enantioselective alkenylation of various aldehyde to generate chiral (E)- allyl alcohols.
Spectrum DetailBack Directory
[Spectrum Detail]

(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE(19131-99-8)1HNMR
(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE(19131-99-8)IR
(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE(19131-99-8)Raman
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