| Identification | Back Directory | [Name]
4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE | [CAS]
19312-06-2 | [Synonyms]
4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE
4,4-Dimethyl-2-phenyl-2-oxazoline 96%
Oxazole, 4,5-dihydro-4,4-dimethyl-2-phenyl-
4,4-Dimethyl-2-phenyl-4,5-dihydro-1,3-oxazole
4,4-Dimethyl-2-phenyl-2-oxazoline | [Molecular Formula]
C11H13NO | [MDL Number]
MFCD00030446 | [MOL File]
19312-06-2.mol | [Molecular Weight]
175.23 |
| Chemical Properties | Back Directory | [Melting point ]
20-24 °C(lit.)
| [Boiling point ]
124 °C20 mm Hg(lit.)
| [density ]
1.025 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.5322(lit.)
| [Fp ]
217 °F
| [storage temp. ]
2-8°C, stored under nitrogen | [pka]
4.82±0.70(Predicted) | [Appearance]
Colorless to off-white <20°C Solid,>24°C Liquid | [BRN ]
132225 | [InChI]
1S/C11H13NO/c1-11(2)8-13-10(12-11)9-6-4-3-5-7-9/h3-7H,8H2,1-2H3 | [InChIKey]
UGNSMKDDFAUGFT-UHFFFAOYSA-N | [SMILES]
CC1(C)COC(=N1)c2ccccc2 |
| Hazard Information | Back Directory | [Uses]
4,4-Dimethyl-2-phenyl-2-oxazoline may be used in the synthesis of an ester-ammonium salt via rupture of oxazoline ring. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 82, p. 2032, 1960 DOI: 10.1021/ja01493a045
Tetrahedron Letters, 27, p. 5269, 1986 DOI: 10.1016/S0040-4039(00)85187-4 | [General Description]
4,4-Dimethyl-2-phenyl-2-oxazoline is an 2-aryl-2-oxazoline and has been tested as as ligand for the Suzuki coupling reaction of aryl bromides and arylboronic acids. 4,4-Dimethyl-2-phenyl-2-oxazoline forms mildly hygroscopic complexes, of general formulae [ZnX2(ox)2] (ox =4,4-Dimethyl-2-phenyl-2-oxazoline), with ether solutions of [ZnX2] (X = Cl, Br, I).Except ZnI2, which does not form an isolable complex due to steric reasons. |
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