| Identification | Back Directory | [Name]
5,10-Di(2-Naphthyl)-5,10-dihydrophenazine >=97% | [CAS]
1934269-97-2 | [Synonyms]
5,10-Di(2-Naphthyl)-5,10-dihydrophenazine
5,10-Di(naphthalen-2-yl)-5,10-dihydrophenazine
5,10-Di(2-Naphthyl)-5,10-dihydrophenazine >=97% | [Molecular Formula]
C32H22N2 | [MDL Number]
MFCD31619182 | [MOL File]
1934269-97-2.mol | [Molecular Weight]
434.53 |
| Chemical Properties | Back Directory | [Boiling point ]
621.8±25.0 °C(Predicted) | [density ]
1.260±0.06 g/cm3(Predicted) | [storage temp. ]
Keep in dark place,Inert atmosphere,2-8°C | [form ]
powder or crystals | [pka]
-1.26±0.20(Predicted) | [Appearance]
Yellow to green Solid | [InChIKey]
HPIOBCHPZVAATK-UHFFFAOYSA-N | [SMILES]
[n]3(c4c([n](c7c3cccc7)c5cc6c(cc5)cccc6)cccc4)c1cc2c(cc1)cccc2 |
| Hazard Information | Back Directory | [Uses]
This dihydrophenazine-based organic photoredox catalyst (in addition to the dihydrophenazine catalyst 901111) was designed to be a strong excited-state reductant and possesses advanced photophysical and electrochemical properties, enabling it to serve as a sustainable replacement for ruthenium- or iridium-based photoredox catalysts. For example, dihydrophenazine and phenoxazine derivatives were demonstrated to replace ruthenium or iridium complexes in the application of photoredox-catalyzed atom transfer radical polymerization (ATRP) for controlled polymer synthesis and small molecule transformations such as trifluoromethylation, atom transfer radical addition, and dual Nickel/photoredox catalyzed C-N and C-S cross-couplings. Dihydrophenazine- and phenoxazine-based organic photoredox catalysts were introduced in collaboration with the Miyake Research Group. | [reaction suitability]
reagent type: catalyst
reaction type: Photocatalysis |
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