| Identification | Back Directory | [Name]
2,3-DIHYDRO-1-BENZOFURAN-7-CARBALDEHYDE | [CAS]
196799-45-8 | [Synonyms]
BUTTPARK 97\04-63
2,3-Dihydrobenzo[b]furan-7-aldehyde
2,3-DIHYDROBENZOFURAN-7-CARBOXALDEHYDE
2,3-DIHYDRO-1-BENZOFURAN-7-CARBALDEHYDE
2,3-Dihydro-1-benzofurane-7-carbaldehyde
7-Benzofurancarboxaldehyde, 2,3-dihydro-
2,3-Dihydrobenzo[b]furan-7-carboxaldehyde
2,3-Dihydrobenzo[b]furan-7-carboxaldehyde 98%
7-Benzofurancarboxaldehyde, 2,3-dihydro- (9CI)
2,3-Dihydro-1-benzofuran-7-carboxaldehyde, 2,3-Dihydro-7-formyl-1-benzofuran | [Molecular Formula]
C9H8O2 | [MDL Number]
MFCD06200853 | [MOL File]
196799-45-8.mol | [Molecular Weight]
148.16 |
| Chemical Properties | Back Directory | [Melting point ]
53-54 °C | [Boiling point ]
277.6±29.0 °C(Predicted) | [density ]
1.222±0.06 g/cm3(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [Appearance]
White to yellow Solid | [CAS DataBase Reference]
196799-45-8 |
| Hazard Information | Back Directory | [Synthesis]
The general procedure for the synthesis of 2,3-dihydrobenzofuran-7-carbaldehyde using 2,3-dihydrobenzofuran-7-methanol as starting material was as follows: 2,3-dihydrobenzofuran-7-methanol (9.76 g, 64.99 mmol) was mixed with manganese dioxide (45.2 g, 519.93 mmol) in toluene (250 mL), and the reaction was stirred for 3 hours at 60 °C. Upon completion of the reaction, manganese dioxide was removed by filtration and the filtrate was concentrated under reduced pressure. Subsequently, the precipitate precipitated was collected by filtration and washed with cooled hexane to give 2,3-dihydrobenzofuran-7-carbaldehyde (7.43 g, 50.1 mmol, 77% yield) as a light yellow solid. | [References]
[1] Patent: TW2016/2105, 2016, A. Location in patent: Paragraph 1203
[2] Patent: WO2007/25307, 2007, A2. Location in patent: Page/Page column 305 - 306
[3] Patent: WO2008/106139, 2008, A1. Location in patent: Page/Page column 475 |
|
|