Identification | Back Directory | [Name]
3,4-Dimethylpyrazole phosphate | [CAS]
202842-98-6 | [Synonyms]
Ente DPMM Entec e phosphate 4-Dimethylpyrazole phosphate 3,4-Dimethylpyrazolephosphate 3,4-Dimethyl-1H-pyrazole Phosphate DMPP/ 3,4-Dimethylpyrazole phosphate 3,4-Dimethylpyrazole phosphate, >=98% 1H-Pyrazole, 3,4-dimethyl-, phosphate 3,4-dimethylpyrazole phosphate (DMPP) 3,4-Dimethyl-1H-pyrazole phosphate (1:1) 4,5-dimethyl-1H-pyrazole,phosphoric acid 1H-Pyrazole, 3,4-dimethyl-, phosphate (1:1) 3,4-Dimethyl-1H-pyrazoliumdihydrogenphosphat 3,4-DIMETHYL-1H-PYRAZOLIUM DIHYDROGEN PHOSPHATE 3,4-Dimethyl-1H-pyrazol-1-ium dihydrogenphosphate 3,4-Dimethyl-1H-pyrazolium dihydrogen phosphate ,97% 3,4-Dimethyl-1H-Pyrazolium Dihydrogen Phosphate (DMPP) | [EINECS(EC#)]
2017-001-1 | [Molecular Formula]
C5H11N2O4P | [MDL Number]
MFCD09842544 | [MOL File]
202842-98-6.mol | [Molecular Weight]
194.126 |
Chemical Properties | Back Directory | [Melting point ]
167-169°C | [storage temp. ]
Hygroscopic, Refrigerator, Under Inert Atmosphere | [solubility ]
Methanol (Slightly), Water | [form ]
Solid | [color ]
White to Pale Beige | [Stability:]
Hygroscopic | [InChI]
InChI=1S/C5H8N2.H3O4P/c1-4-3-6-7-5(4)2;1-5(2,3)4/h3H,1-2H3,(H,6,7);(H3,1,2,3,4) | [InChIKey]
LXKCHCXZBPLTAE-UHFFFAOYSA-N | [SMILES]
CC1=CNN=C1C.P(O)(O)(O)=O |
Hazard Information | Back Directory | [Description]
3,4-Dimethylpyrazole (phosphate) (3,4-DMPP) is an inhibitor of nitrification deemed safe by extensive standard toxicology and ecotoxicology tests.1 When utilized on crops, 3,4-DMPP prevents nitrogen loss from soil, increases nitrogen use efficiency, and boosts crop yields.1,2 However, a meta-analysis found no influence of 3,4-DMPP on net crop yield, although it may boost yields in alkaline soil.3 3,4-DMPP may be less effective in acidic soils and in the post-harvest period.4,5 DMPP interferes with ammonia monooxygenase from ammonia-oxidizing bacteria (AOB) and archaea (AOA) but may not directly affect AOB, AOA, and non-target populations.6 | [Chemical Properties]
Pale Beige Solid | [Uses]
As a new nitrification inhibitor, 3,4-Dimethylpyrazole phosphate can be used on solid and in liquid fertilizers and slurry
| [Definition]
ChEBI: 3,4-dimethyl-1H-pyrazole phosphate is a phosphate salt obtained by reacting 3,4-dimethyl-1H-pyrazole with one equivalent of phosphoric acid. It is a nitrification inhibitor and when used on crops, it prevents nitrogen loss from soil, increases nitrogen use efficiency, and boosts crop yields. It has a role as a nitrification inhibitor. It contains a 3,4-dimethyl-1H-pyrazole. | [References]
[1] W. ZERULLA. 3,4-Dimethylpyrazole phosphate (DMPP) – a new nitrification inhibitor for agriculture and horticulture[J]. Biology and Fertility of Soils, 2001, 34 1: 79-84. DOI: 10.1007/s003740100380 [2] CHUNYAN LIU X Z Kai Wang. Effects of nitrification inhibitors (DCD and DMPP) on nitrous oxide emission, crop yield and nitrogen uptake in a wheat-maize cropping system[J]. Biogeosciences, 2013, 10 1: 2427-2437. DOI: 10.5194/bg-10-2427-2013 [3] MING YANG. Efficiency of two nitrification inhibitors (dicyandiamide and 3, 4-dimethypyrazole phosphate) on soil nitrogen transformations and plant productivity: a meta-analysis[J]. Scientific Reports, 2016, 72 1. DOI: 10.1038/srep22075 [4] XIUZHEN SHI. Effects of the Nitrification Inhibitor 3,4-Dimethylpyrazole Phosphate on Nitrification and Nitrifiers in Two Contrasting Agricultural Soils.[J]. Applied and Environmental Microbiology, 2016: 5236-5248. DOI: 10.1128/aem.01031-16 [5] CLEMENS SCHEER. Nitrification inhibitors can increase post-harvest nitrous oxide emissions in an intensive vegetable production system.[J]. Scientific Reports, 2017: 43677. DOI: 10.1038/srep43677 [6] XIANWANG KONG . 3,4-Dimethylpyrazole phosphate (DMPP) reduces activity of ammonia oxidizers without adverse effects on non-target soil microorganisms and functions[J]. Applied Soil Ecology, 2016, 105: Pages 67-75. DOI: 10.1016/j.apsoil.2016.03.018 |
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