ChemicalBook--->CAS DataBase List--->202842-98-6

202842-98-6

202842-98-6 Structure

202842-98-6 Structure
IdentificationBack Directory
[Name]

3,4-Dimethylpyrazole phosphate
[CAS]

202842-98-6
[Synonyms]

Ente
DPMM
Entec
e phosphate
4-Dimethylpyrazole phosphate
3,4-Dimethylpyrazolephosphate
3,4-Dimethyl-1H-pyrazole Phosphate
DMPP/ 3,4-Dimethylpyrazole phosphate
3,4-Dimethylpyrazole phosphate, >=98%
1H-Pyrazole, 3,4-dimethyl-, phosphate
3,4-dimethylpyrazole phosphate (DMPP)
3,4-Dimethyl-1H-pyrazole phosphate (1:1)
4,5-dimethyl-1H-pyrazole,phosphoric acid
1H-Pyrazole, 3,4-dimethyl-, phosphate (1:1)
3,4-Dimethyl-1H-pyrazoliumdihydrogenphosphat
3,4-DIMETHYL-1H-PYRAZOLIUM DIHYDROGEN PHOSPHATE
3,4-Dimethyl-1H-pyrazol-1-ium dihydrogenphosphate
3,4-Dimethyl-1H-pyrazolium dihydrogen phosphate ,97%
3,4-Dimethyl-1H-Pyrazolium Dihydrogen Phosphate (DMPP)
[EINECS(EC#)]

2017-001-1
[Molecular Formula]

C5H11N2O4P
[MDL Number]

MFCD09842544
[MOL File]

202842-98-6.mol
[Molecular Weight]

194.126
Chemical PropertiesBack Directory
[Melting point ]

167-169°C
[storage temp. ]

Hygroscopic, Refrigerator, Under Inert Atmosphere
[solubility ]

Methanol (Slightly), Water
[form ]

Solid
[color ]

White to Pale Beige
[Stability:]

Hygroscopic
[InChI]

InChI=1S/C5H8N2.H3O4P/c1-4-3-6-7-5(4)2;1-5(2,3)4/h3H,1-2H3,(H,6,7);(H3,1,2,3,4)
[InChIKey]

LXKCHCXZBPLTAE-UHFFFAOYSA-N
[SMILES]

CC1=CNN=C1C.P(O)(O)(O)=O
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS05,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H318-H335-H361fd-H373-H302+H312+H332-H315
[Precautionary statements ]

P280-P301+P312-P304+P340
[HS Code ]

2933199090
Raw materials And Preparation ProductsBack Directory
Hazard InformationBack Directory
[Description]

3,4-Dimethylpyrazole (phosphate) (3,4-DMPP) is an inhibitor of nitrification deemed safe by extensive standard toxicology and ecotoxicology tests. When utilized on crops, 3,4-DMPP prevents nitrogen loss from soil, increases nitrogen use efficiency, and boosts crop yields. However, a meta-analysis found no influence of 3,4-DMPP on net crop yield, although it may boost yields in alkaline soil. 3,4-DMPP may be less effective in acidic soils and in the post-harvest period. DMPP interferes with ammonia monooxygenase from ammonia-oxidizing bacteria (AOB) and archaea (AOA) but may not directly affect AOB, AOA, and non-target populations.
[Chemical Properties]

Pale Beige Solid
[Uses]

As a new nitrification inhibitor, 3,4-Dimethylpyrazole phosphate can be used on solid and in liquid fertilizers and slurry
[Definition]

ChEBI: 3,4-dimethyl-1H-pyrazole phosphate is a phosphate salt obtained by reacting 3,4-dimethyl-1H-pyrazole with one equivalent of phosphoric acid. It is a nitrification inhibitor and when used on crops, it prevents nitrogen loss from soil, increases nitrogen use efficiency, and boosts crop yields. It has a role as a nitrification inhibitor. It contains a 3,4-dimethyl-1H-pyrazole.
[References]

[1] W. ZERULLA. 3,4-Dimethylpyrazole phosphate (DMPP) – a new nitrification inhibitor for agriculture and horticulture[J]. Biology and Fertility of Soils, 2001, 34 1: 79-84. DOI: 10.1007/s003740100380
[2] CHUNYAN LIU X Z Kai Wang. Effects of nitrification inhibitors (DCD and DMPP) on nitrous oxide emission, crop yield and nitrogen uptake in a wheat-maize cropping system[J]. Biogeosciences, 2013, 10 1: 2427-2437. DOI: 10.5194/bg-10-2427-2013
[3] MING YANG. Efficiency of two nitrification inhibitors (dicyandiamide and 3, 4-dimethypyrazole phosphate) on soil nitrogen transformations and plant productivity: a meta-analysis[J]. Scientific Reports, 2016, 72 1. DOI: 10.1038/srep22075
[4] XIUZHEN SHI. Effects of the Nitrification Inhibitor 3,4-Dimethylpyrazole Phosphate on Nitrification and Nitrifiers in Two Contrasting Agricultural Soils.[J]. Applied and Environmental Microbiology, 2016: 5236-5248. DOI: 10.1128/aem.01031-16
[5] CLEMENS SCHEER. Nitrification inhibitors can increase post-harvest nitrous oxide emissions in an intensive vegetable production system.[J]. Scientific Reports, 2017: 43677. DOI: 10.1038/srep43677
[6] XIANWANG KONG . 3,4-Dimethylpyrazole phosphate (DMPP) reduces activity of ammonia oxidizers without adverse effects on non-target soil microorganisms and functions[J]. Applied Soil Ecology, 2016, 105: Pages 67-75. DOI: 10.1016/j.apsoil.2016.03.018
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