| Identification | Back Directory | [Name]
Ir[dFFppy]2-(4,4'-dCF3bpy)PF6 | [CAS]
2030437-92-2 | [Synonyms]
Ir[dFFppy]2-(4,4'-dCF3bpy)PF6
IR [DFFPPY] 2-(4,4'- DCF3BPY)PF6 | [Molecular Formula]
C34H16F18IrN4P | [MDL Number]
MFCD27952560 | [MOL File]
2030437-92-2.mol | [Molecular Weight]
1045.69 |
| Chemical Properties | Back Directory | [Melting point ]
>300 °C | [form ]
powder or crystals | [InChIKey]
UCNIZYCFAFBGQB-UHFFFAOYSA-N | [SMILES]
[Ir+]741([NH]8=C(c9c7cc(cc9F)F)C=CC(=C8)F)([NH]5=CC(=CC=C5c6c4cc(cc6F)F)F)[NH]2=CC=C(C=C2C3=CC(=CC=[NH]31)C(F)(F)F)C(F)(F)F.F[P-](F)(F)(F)(F)F |
| Hazard Information | Back Directory | [Uses]
Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489). | [reaction suitability]
core: iridium
reagent type: catalyst
reaction type: Photocatalysis |
|
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Alfa Chemistry
|
| Tel: |
1-516-6625404 |
| Website: |
https://www.alfa-chemistry.com |
| Company Name: |
Shanghai UCHEM Inc.
|
| Tel: |
18939844854 |
| Website: |
www.chemicalbook.com/supplier/23967788/ |
|