| Identification | Back Directory | [Name]
BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)CHLOROPHOSPHINE | [CAS]
212713-08-1 | [Synonyms]
Bis(3,5-di-t-butyl-4-methoxyphenyl)chlorophosphine,
BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)CHLOROPHOSPHINE
chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane
Bis(3,5-di-t-butyl-4-methoxyphenyl)chlorophosphine,93%
BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINOUS CHLORIDE
Bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphinous chloride
Phosphinous chloride, P,P-bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]- | [EINECS(EC#)]
633-650-4 | [Molecular Formula]
C30H46ClO2P | [MDL Number]
MFCD08458881 | [MOL File]
212713-08-1.mol | [Molecular Weight]
505.11 |
| Chemical Properties | Back Directory | [Melting point ]
116-120 °C | [Boiling point ]
552.5±50.0 °C(Predicted) | [form ]
solid | [Water Solubility ]
Reacts with water. | [Sensitive ]
Air & Moisture Sensitive |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS02 | [Signal word ]
Warning | [Hazard statements ]
H228 | [Precautionary statements ]
P210 | [Hazard Codes ]
F | [Risk Statements ]
11 | [RIDADR ]
UN3261 | [WGK Germany ]
3 | [HazardClass ]
8 | [PackingGroup ]
II |
| Hazard Information | Back Directory | [Uses]
It is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
|
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Alfa Aesar
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Energy Chemical
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http://www.energy-chemical.com |
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Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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