21797-13-7

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21797-13-7 Structure

Identification	Back Directory
[Name] TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE
[CAS] 21797-13-7
[Synonyms] NSC 307191 TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE Tetrakis(acetonitrile)palladium(II)tetrafluoroborate,99% PALLADIUM(II) TETRAFLUOROBORATE-TETRAACETONITRILE COMPLEX TETRAKIS(ACETONITRILE)PALLADIUM(II) BIS(TETRAFLUOROBORATE) TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE (30%PD) Tetrakis(acetonitrile)palladiuM(II) tetrafluoroborate, 99% 1GR Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, min. 98% Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, Pd 23.9%
[Molecular Formula] C8H12B2F8N4Pd
[MDL Number] MFCD00043297
[MOL File] 21797-13-7.mol
[Molecular Weight] 444.24

Chemical Properties	Back Directory
[Appearance] Yellow powder
[Melting point ] 230 °C (dec.)(lit.)
[storage temp. ] 2-8°C
[form ] Powder
[color ] Yellow
[Water Solubility ] Soluble in water
[Sensitive ] Air Sensitive
[InChI] 1S/4C2H3N.2BF4.Pd/c41-2-3;22-1(3,4)5;/h41H3;;;/q;;;;2-1;+2
[InChIKey] YWMRPVUMBTVUEX-UHFFFAOYSA-N
[SMILES] [Pd++].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F.F[B-](F)(F)F

Hazard Information	Back Directory
[Chemical Properties] Yellow powder
[Uses] Application Guide for Palladium Catalyzed Cross-Coupling Reactions Reactant involved in: Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligands Precursor for: Synthesis of dendritic SCS-pincer palladium complexes Palladium complexes of click ligands Dipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination
[Uses] Tetrakis(acetonitrile)palladium Bis(tetrafluoroborate) is used to prepare an α-Diimine-transition metal complex, which is used as a catalyst for polymerization of olefins. It is also a catalyst used in cross coupling reaction for C-C, C-O, and C-N bond formation.
[General Description] Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a stronger Lewis acid. It participates in the preparation of 2:1 complex [Pd(1,2-bis(2′-pyridylethynyl)benzene)₂](BF₄]₂, by Sonogashira cross-coupling reaction.
[reaction suitability] reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Cross Couplings reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst core: palladium reagent type: ligand

Safety Data	Back Directory
[Hazard Codes ] Xn
[Risk Statements ] 20
[Safety Statements ] 22-36/37/39-38
[RIDADR ] UN2811
[WGK Germany ] 3
[HazardClass ] 6.1
[PackingGroup ] III
[HS Code ] 29310099
[Storage Class] 11 - Combustible Solids
[Hazard Classifications] Acute Tox. 4 Inhalation

Spectrum Detail	Back Directory
[Spectrum Detail] TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE(21797-13-7)¹HNMR TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE(21797-13-7)IR

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