| Identification | Back Directory | [Name]
4-ACETAMIDO-2,2,6,6-TETRAMETHYL-1-OXOPIPERIDINIUM TETRAFLUOROBORATE,95.0+%(T) | [CAS]
219543-09-6 | [Synonyms]
Bobbitt′s Salt
N-(2,2,6,6-tetramethyl-1-oxo-piperidin-1-ium-4-yl)acetamide
4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafluoroborate
4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidin-1-ium tetrafluoroborate
4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafluoroborate >
4-(Acetylamino)-2,2,6,6-tetramethyl-1-oxo-piperidinium tetrafluoroborate
4-acetamido-2 2 6 6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate
4-Acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate
N-(2,2,6,6-tetramethyl-1-oxopiperidin-1-ium-4-yl)acetamide,tetrafluoroborate
4-ACETAMIDO-2,2,6,6-TETRAMETHYL-1-OXOPIPERIDINIUM TETRAFLUOROBORATE,95.0+%(T)
N-(2,2,6,6-Tetramethyl-1-oxidopiperidin-1-ium-4-yl)acetamide Tetrafluoroborate | [Molecular Formula]
C11H21BF4N2O2 | [MDL Number]
MFCD29060212 | [MOL File]
219543-09-6.mol |
| Chemical Properties | Back Directory | [Melting point ]
191-197°C (decomposition) | [storage temp. ]
2-8°C | [solubility ]
soluble in Methanol | [form ]
powder to crystal | [color ]
Light yellow to Yellow to Orange | [InChI]
1S/C11H20N2O2.BF4/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9;2-1(3,4)5/h9H,6-7H2,1-5H3;/q;-1/p+1 | [InChIKey]
HTMHEICBCHCWAU-UHFFFAOYSA-O | [SMILES]
F[B-](F)(F)F.CC(=O)NC1CC(C)(C)[N+](=O)C(C)(C)C1 |
| Hazard Information | Back Directory | [Uses]
Bobbitt′s salt (4-NHAc-TEMPO+ BF4 ?)?can be used as a reagent in:???????
- Oxidation of alcohols to their concomitant aldehyde, ketone or carboxylic acid.??????
- Conversion of aldehydes to hexafluoroisopropyl (HFIP) esters via oxidative esterification.,·????????
- Deprotection of allyl ethers to corresponding aldehydes.
- ?Preparation of α,β-unsaturated ketones by dehydrogenation of perfluoroalkyl ketones.
| [General Description]
Bobbitt′s salt (oxoammonium salt) is a commonly used oxidizing agent in organic synthesis for the preparation of useful chemical intermediates. This reagent is highly stable to both air and moisture. | [reaction suitability]
reagent type: oxidant |
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https://www.jkchemical.com |
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Sigma-Aldrich
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