| Identification | Back Directory | [Name]
4,4'-Bis(trifluoromethyl)-2,2'-bipyridinebis[3,5-difluoro-2-[5-methyl-2-pyridinyl)phenyl] iridium(III) hexafluorophosphate | [CAS]
2229858-27-7 | [Synonyms]
Ir[dFMeppy]?-(4,4′-dCF?bpy)PF?
4,4'-bis(trifluoromethyl)-2,2'-bipyridinebis[3,5-difluoro-2-[5-methyl-2-pyridinyl)phenyl] iridium(iii) hexafluorophosphate
4,4'-Bis(trifluoromethyl)-2,2'-bipyridinebis[3,5-difluoro-2-[5-methyl-2-pyridinyl)phenyl] iridium(III) hexafluorophosphate, 98% | [Molecular Formula]
C36H22F16IrN4P | [MOL File]
2229858-27-7.mol | [Molecular Weight]
1037.77 |
| Chemical Properties | Back Directory | [Melting point ]
>300°C | [storage temp. ]
under inert gas (nitrogen or Argon) at 2–8 °C | [form ]
powder | [Appearance]
Yellow to orange Solid | [InChIKey]
RYKRFKQFYGHADE-UHFFFAOYSA-N |
| Hazard Information | Back Directory | [Uses]
Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080) | [reaction suitability]
core: iridium
reaction type: Photocatalysis
reagent type: catalyst |
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Alfa Chemistry
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1-516-6625404 |
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https://www.alfa-chemistry.com |
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Shanghai UCHEM Inc.
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18939844854 |
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www.chemicalbook.com/supplier/23967788/ |
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