| Identification | Back Directory | [Name]
BENZYLOXYACETONE | [CAS]
22539-93-1 | [Synonyms]
BENZYLOXYACETONE
1-(Benzyloxy)acetone
Benzyloxyacetone 90%
3-benzyloxypropanone
1-BENZYLOXY-2-PROPANONE
1-(Benzyloxy)propan-2-one
1-(Benzyloxy)propane-2-one
1-phenylmethoxypropan-2-one
1-phenylmethoxy-2-propanone
2-Propanone, 1-(phenylMethoxy)- | [Molecular Formula]
C10H12O2 | [MDL Number]
MFCD01863536 | [MOL File]
22539-93-1.mol | [Molecular Weight]
164.2 |
| Chemical Properties | Back Directory | [Boiling point ]
259 °C (lit.) | [density ]
1.04 g/mL at 25 °C (lit.) | [refractive index ]
n20/D 1.512(lit.) | [Fp ]
>230 °F | [storage temp. ]
Inert atmosphere,Room Temperature |
| Hazard Information | Back Directory | [Uses]
Benzyloxyacetone (1-Benzyloxy-2-propanone) may be used in the synthesis of:
- 7-benzyloxy-6-methyl-5-hepten-1-yne
- (Z)-2-methylhept-2-en-6-yn-1-o1
- (S)-(+)-1,2-propanediol, 1-benzyl ether
It may be used as a starting material in synthesizing (2S,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane and (2R,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane. | [General Description]
Benzyloxyacetone (α-Benzyloxyacetone) is an α-substituted acetone. It undergoes direct aldol reaction with 4-nitrobenzaldehyde in the presence of (S)-BINAM-L-prolinamide/benzoic acid to form predominantly the syn-diasteroisomer. |
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