| Identification | Back Directory | [Name]
(S,S)-(-)-1,2-DI(1-NAPHTHYL)-1,2-ETHANEDIOL | [CAS]
229184-99-0 | [Synonyms]
(S,S)-1,2-DI(1-NAPHTHYL)-1,2-ETHANEDIOL
(S,S)-(-)-1,2-DI(1-NAPTHYL)-1,2-ETHANEDIOL
(S,S)-(-)-1,2-DI(1-NAPHTHYL)-1,2-ETHANEDIOL
1,2-Ethanediol, 1,2-di-1-naphthalenyl-, (1S,2S)- | [Molecular Formula]
C22H18O2 | [MDL Number]
MFCD01863520 | [MOL File]
229184-99-0.mol | [Molecular Weight]
314.38 |
| Chemical Properties | Back Directory | [Melting point ]
149-151 °C (lit.) | [storage temp. ]
Store at 0-8 °C | [Optical Rotation]
[α]23/D 25°, c = 1 in chloroform | [InChI]
1S/C22H18O2/c23-21(19-13-5-9-15-7-1-3-11-17(15)19)22(24)20-14-6-10-16-8-2-4-12-18(16)20/h1-14,21-24H/t21-,22-/m0/s1 | [InChIKey]
MNRCSHSTIWDUPJ-VXKWHMMOSA-N | [SMILES]
O[C@H]([C@@H](O)c1cccc2ccccc12)c3cccc4ccccc34 |
| Hazard Information | Back Directory | [Uses]
(S, S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol can be used as:
- A ligand in the asymmetric sulfoxidation of dihydrothienopyrimidine.
- A reactant for the preparation of (2S,2′S)-[(1S,2S)-1,2-bis(naphthalen-1-yl)ethane-1,2-diyl] bis[2-(dimethylamino)propanoate], a chiral bisester ligand via condensation reaction with N,N-dimethylamino acid using aldol-Tishchenko condensation catalyst.
- A reactant to synthesize diol-SnCl4 chiral Bronsted acid complex, which is employed as a catalyst in the allylboration of aldehydes.
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Energy Chemical
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www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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