| Identification | Back Directory | [Name]
thianthrene 5-oxide | [CAS]
2362-50-7 | [Synonyms]
thianthrene 5-oxide
Thianthrene 10-oxide
Benzothianthrene Oxide | [Molecular Formula]
C12H8OS2 | [MDL Number]
MFCD01464038 | [MOL File]
2362-50-7.mol | [Molecular Weight]
232.32 |
| Chemical Properties | Back Directory | [Melting point ]
143-143.5 °C | [Boiling point ]
423.2±15.0 °C(Predicted) | [density ]
1.49±0.1 g/cm3(Predicted) | [storage temp. ]
2-8°C | [form ]
powder | [Appearance]
White to off-white Solid | [InChI]
1S/C12H8OS2/c13-15-11-7-3-1-5-9(11)14-10-6-2-4-8-12(10)15/h1-8H | [InChIKey]
NYVGTLXTOJKHJN-UHFFFAOYSA-N | [SMILES]
[S+]1(c2c(cccc2)Sc3c1cccc3)[O-] |
| Hazard Information | Back Directory | [Uses]
Thianthrene S-oxide is a sulfoxide-based thianthrene reagent for late-stage C-H functionalization. Developed by the Ritter Lab, C-H functionalization by thianthrenation proceeds with >99% selectivity and furnishes functionalized arenes serving as synthetic linchpins for further participation in diverse transformations. Nonfluorinated thianthrene S-oxide is best used for all arenes more electron-rich than anisole. For other arenes, the fluorinated TFT S-oxide (903981) was demonstrated as the thanthrenation reagent. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 78, p. 2163, 1956 DOI: 10.1021/ja01591a037
Synthetic Communications, 22, p. 1799, 1992 DOI: 10.1080/00397919208020500 |
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| Company Name: |
Energy Chemical
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| Tel: |
021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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