| Identification | Back Directory | [Name]
ALLYLTRIMETHOXYSILANE | [CAS]
2551-83-9 | [Synonyms]
A 1504
Z 6825
Allytrimethoxysilane
TRIMETHOXYALLYLSILANE
ALLYLTRIMETHOXYSILANE
Allyltrimethoxysilane 95%
Allyltrimethoxysilane, 97+%
trimethoxy-2-propenyl-silan
trimethoxy-2-propenyl-Silane
3-(Trimethoxysilyl)-1-propene
Silane,trimethoxy-2-propenyl-
AllyltriMethoxysilane, 97+% 5ML
Allyltrimethoxysilane >=98%, deposition grade | [EINECS(EC#)]
219-855-8 | [Molecular Formula]
C6H14O3Si | [MDL Number]
MFCD00053865 | [MOL File]
2551-83-9.mol | [Molecular Weight]
162.26 |
| Chemical Properties | Back Directory | [Appearance]
Clear colorless liquid | [Boiling point ]
146-148 °C(lit.)
| [density ]
0.963 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.405(lit.)
| [Fp ]
88 °F
| [storage temp. ]
2-8°C
| [form ]
Liquid | [color ]
Clear colorless | [Specific Gravity]
0.96 | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [BRN ]
2350745 | [InChI]
InChI=1S/C6H14O3Si/c1-5-6-10(7-2,8-3)9-4/h5H,1,6H2,2-4H3 | [InChIKey]
LFRDHGNFBLIJIY-UHFFFAOYSA-N | [SMILES]
[Si](OC)(OC)(OC)CC=C | [EPA Substance Registry System]
Silane, trimethoxy-2-propenyl- (2551-83-9) |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless liquid | [Description]
Allyltrimethoxysilane is an allylating reagent that can be used for the allylation of carbonyl compounds such as aldehydes, ketones, and imines. Homoallylic alcohols and amines are obtained via the C-C bond forming reaction. It can also be used to synthesize homoallylic α-branched amines from aromatic and aliphatic aldehyde hydrazones, and ketone hydrazones.? | [Uses]
Allyltrimethoxysilane is an allylating reagent that can be used for the allylation of carbonyl compounds such as aldehydes, ketones, and imines. Homoallylic alcohols and amines are obtained via the C-C bond forming reaction. It can also be used to synthesize homoallylic α-branched amines from aromatic and aliphatic aldehyde hydrazones, and ketone hydrazones. | [Application]
Allylation of ketones, aldehydes and imines with dual activation of a Lewis Acid and fluoride ion.
Used in the regioselective generation of the thermodynamically more stable enol trimethoxysilyl ethers, which in turn are used in the asymmetric generation of quaternary carbon centers.
Converts arylselenyl bromides to arylallylselenides.
Allylates aryl iodides. |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
10-36/37/38 | [Safety Statements ]
26-36-37/39-16 | [RIDADR ]
UN 1993 3/PG 3
| [WGK Germany ]
3
| [F ]
10-21 | [TSCA ]
Yes | [HazardClass ]
3.1 | [PackingGroup ]
II | [HS Code ]
29319090 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3 |
|
|