| Identification | Back Directory | [Name]
1,3-ADAMANTANEDIAMINE DIHYDROCHLORIDE | [CAS]
26562-81-2 | [Synonyms]
ADAMANTANE-1,3-DIAMINE 2HCL
1,3-Diaminoadamantane dihydrochloride
1,3-ADAMANTANEDIAMINE DIHYDROCHLORIDE
5. 1,3-adamantanediamine dihydrochloride | [Molecular Formula]
C10H18N2.2(HCl) | [MDL Number]
MFCD00137394 | [MOL File]
26562-81-2.mol | [Molecular Weight]
405.45 |
| Chemical Properties | Back Directory | [Melting point ]
308-350 °C (decomp)(Solv: acetone (67-64-1); water (7732-18-5)) | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
solid | [color ]
White |
| Hazard Information | Back Directory | [Synthesis]
General procedure for the synthesis of 1,3-diaminoadamantane dihydrochloride from 1,3-bis(acetylamino)adamantane: A mixture of 1 g of 1,3-bis(acetylamino)adamantane, 28 mL of water, and 2 mL of 36% hydrochloric acid was heated and refluxed for 25 hours, followed by evaporation of the reaction solution to dryness. By treating the residue, 1,3-diaminoadamantane dihydrochloride was obtained. | [Purification Methods]
Dissolve it in boiling conc HCl (400mg in 15mL) and evaporate to dryness. Dissolve it in absolute EtOH and add dry Et2O to crystallise the dihydrochloride. [Stetter & Wulff Chem Ber 93 1366 1960, Beilstein 13 III 27,] | [References]
[1] Russian Journal of Organic Chemistry, 2017, vol. 53, # 8, p. 1170 - 1175
[2] Zh. Org. Khim., 2017, vol. 53, # 8, p. 1156 - 1161,6 |
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