| Identification | Back Directory | [Name]
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) | [CAS]
27057-09-6 | [Synonyms]
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99% | [Molecular Formula]
C43H37ClNiP2 | [MDL Number]
MFCD28144558 | [MOL File]
27057-09-6.mol | [Molecular Weight]
711.88 |
| Chemical Properties | Back Directory | [Melting point ]
195-200°C | [storage temp. ]
2-8°C | [form ]
Powder | [color ]
yellow | [InChI]
1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1 | [InChIKey]
QVGJKVLYWZGANE-UHFFFAOYSA-M | [SMILES]
Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7 | [CAS DataBase Reference]
27057-09-6 |
| Questions And Answer | Back Directory | [Reaction]
- This complex is used as an air-stable nickel precatalyst for the amination of aryl chlorides, sulfamates, mesylates, and triflates.
- This nickel precatalyst is used for the polymerization of halothiophenes.
|
| Hazard Information | Back Directory | [Uses]
Product is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers. | [reaction suitability]
core: nickel
reagent type: catalyst |
|
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Alfa Chemistry
|
| Tel: |
1-516-6625404 |
| Website: |
https://www.alfa-chemistry.com |
| Company Name: |
Energy Chemical
|
| Tel: |
021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Shanghai UCHEM Inc.
|
| Tel: |
18939844854 |
| Website: |
www.chemicalbook.com/supplier/23967788/ |
|