| Identification | Back Directory | [Name]
BARIUM TRIFLUOROMETHANESULFONATE | [CAS]
2794-60-7 | [Synonyms]
BARIUM TRIFLATE
BARIUM TRIFLUOROMETHANESULFONATE
barium trifluoromethanesulphonate
TRIFLUOROMETHANESULFONIC ACID BARIUM
Barium trifluoromethanesulfonate,98%
Barium trifluoromethanesulfonate 98%
trifluoro-methanesulfonicacibariumsalt
Trifluoromethanesulfonic acid barium salt
Bis(trifluoromethanesulfonic acid)barium salt
BARIUM TRIFLUOROMETHANESULFONATE, 99% (BARIUM TRIFLATE)
Barium triflate, Trifluoromethanesulfonic acid barium salt | [EINECS(EC#)]
220-526-6 | [Molecular Formula]
C2BaF6O6S2 | [MDL Number]
MFCD00143644 | [MOL File]
2794-60-7.mol | [Molecular Weight]
435.47 |
| Chemical Properties | Back Directory | [Appearance]
White powder | [Melting point ]
>300 °C(lit.)
| [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Powder | [color ]
white | [Water Solubility ]
Soluble in water. | [Hydrolytic Sensitivity]
5: forms reversible hydrate | [Sensitive ]
Hygroscopic | [BRN ]
3729346 | [Exposure limits]
ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3 | [Stability:]
hygroscopic | [InChI]
InChI=1S/2CHF3O3S.Ba/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2 | [InChIKey]
DXJURUJRANOYMX-UHFFFAOYSA-L | [SMILES]
C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S([O-])(=O)=O.[Ba+2] | [EPA Substance Registry System]
Methanesulfonic acid, trifluoro-, barium salt (2794-60-7) |
| Hazard Information | Back Directory | [Chemical Properties]
White powder | [Uses]
Ba(CF3SO3) can be utilized as a precursor to synthesize:
- Alkali metal and silver trifluoromethanesulfonates.
- Sodium trifluoromethanesulfonate (sodium triflate) by reacting with sodium sulfate. Sodium triflate finds application in organic synthesis as an efficient catalyst as well as a reactant in catalytic asymmetric Mannich-type reactions, and Diels-Alder reactions.
|
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
20/22 | [Safety Statements ]
28 | [RIDADR ]
UN 1564 6.1/PG 3
| [WGK Germany ]
1
| [TSCA ]
No | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29049020 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral |
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