| Identification | Back Directory | [Name]
2-(2-BENZOTHIAZOLYL)ACETIC ACID ETHYL ESTER | [CAS]
29182-42-1 | [Synonyms]
NSC 621357
Ethyl benz
AKOS BBS-00007333
ETHYL BENZOTHIAZOLYLACETATE
ETHYL 2-BENZOTHIAZOLEACETATE
ETHYL 2-(2-BENZOTHIAZOLYL)ACETATE
ETHYL 1,3-BENZOTHIAZOL-2-YLACETATE
Ethyl 2-(benzothiazol-2-yl) acetate
ethyl 2-(benzo[d]thiazol-2-yl)acetate
ethyl 2-(1,3-benzothiazol-2-yl)acetate
2-BENZOTHIAZOLEACETIC ACID ETHYL ESTER
Benzothiazol-2-yl-acetic acid ethyl ester
2-(2-BENZOTHIAZOLYL)ACETIC ACID ETHYL ESTER
2-Benzothiazoleaceticacid,ethylester(8CI,9CI)
2-(2-Benzothiazolyl)acetic Acid Ethyl Ester
Ethyl 2-Benzothiazoleacetate
2-Benzothiazoleacetic Acid Ethyl Ester | [Molecular Formula]
C11H11NO2S | [MDL Number]
MFCD00546397 | [MOL File]
29182-42-1.mol | [Molecular Weight]
221.28 |
| Chemical Properties | Back Directory | [Appearance]
Yellow oil or crystalline | [Boiling point ]
145 °C / 1.5mmHg | [density ]
1.260±0.06 g/cm3(Predicted) | [refractive index ]
1.58 | [storage temp. ]
Sealed in dry,Room Temperature | [pka]
0.72±0.10(Predicted) | [InChI]
InChI=1S/C11H11NO2S/c1-2-14-11(13)7-10-12-8-5-3-4-6-9(8)15-10/h3-6H,2,7H2,1H3 | [InChIKey]
VYMJUZXFYAREJY-UHFFFAOYSA-N | [SMILES]
S1C2=CC=CC=C2N=C1CC(OCC)=O |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow oil or crystalline | [Uses]
Ethyl 2-(benzo[d]thiazol-2-yl)acetate is a useful research chemical. | [Synthesis]
To a mixture of 2-aminothiophenol (5 g, 39.9 mmol) was added ethyl cyanoacetate (4.25 ml, 39.9 mmol). The reaction mixture was heated to 120°C under stirring and maintained at this temperature for 3 hours. Upon completion of the reaction, the volatile components were removed by concentration under reduced pressure to give 8 g of ethyl 2-(benzo[d]thiazol-2-yl)acetate, the product being a brown oil in 90% yield. | [References]
[1] Patent: CN104177379, 2016, B. Location in patent: Paragraph 0050; 0052; 0053
[2] Bulletin of the Korean Chemical Society, 2011, vol. 32, # 5, p. 1461 - 1462
[3] Patent: US2007/32652, 2007, A1. Location in patent: Page/Page column 20-21
[4] Patent: US2011/112086, 2011, A1. Location in patent: Page/Page column 16
[5] Journal of the American Chemical Society, 2010, vol. 132, # 4, p. 1276 - 1288 |
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