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32133-82-7

32133-82-7 Structure

32133-82-7 Structure
IdentificationBack Directory
[Name]

BIS[ALPHA,ALPHA-BIS(TRIFLUOROMETHYL)BENZENEMETHANOLATO]DIPHENYLSULFUR
[CAS]

32133-82-7
[Synonyms]

Bis[&alpha
MARTIN SULFURANE
MAR SULFU(MARTIN SULFURANE)
Bis[α,α-bis(trifluoromethyl)b
MARTIN SULFURANE DEHYDRATING AGENT
MARTIN SULFURANE DEHYDRATING AGENT, TECH .
Martin Sulfurane Dehydrating agent technical grade
-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
Bis[bis(trifluoromet?hyl)?phenylmethoxy]?diphenylsulfurane
BIS[ALPHA,ALPHA-BIS(TRIFLUOROMETHYL)BENZYLOXY]DIPHENYLSULFUR
bis[α,α-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
Bis[a,a-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
Bis[α,α-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
Bis[α,α-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur>
BIS[ALPHA,ALPHA-BIS(TRIFLUOROMETHYL)BENZENEMETHANOLATO]DIPHENYLSULFUR
Sulfur, bis[a,a-bis(trifluoromethyl)benzenemethanolato-kO]diphenyl-, (T-4)-
Sulfur, bis[α,α-bis(trifluoromethyl)benzenemethanolato-κO]diphenyl-, (T-4)-
bis[(1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-yl)oxy]-diphenyl-$l^{4}-sulfane
bis[(1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-yl)oxy]-diphenyl-lambda4-sulfane
Bis[α,α-bis(trifluoromethyl)benzyloxy]diphenylsulfur, Bis[α,α-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
[Molecular Formula]

C30H20F12O2S
[MDL Number]

MFCD00010662
[MOL File]

32133-82-7.mol
[Molecular Weight]

672.52
Chemical PropertiesBack Directory
[Melting point ]

106-108 °C(lit.)
[density ]

1.32±0.1 g/cm3(Predicted)
[storage temp. ]

Freezer
[solubility ]

soluble in Methanol
[form ]

powder to crystal
[color ]

White to Orange to Green
[BRN ]

1416879
[Stability:]

Extremely Moisture Sensitive
[InChIKey]

RMIBJVUYNZSLSD-UHFFFAOYSA-N
[SMILES]

S(C1=CC=CC=C1)(C1=CC=CC=C1)(OC(C(F)(F)F)(C(F)(F)F)C1=CC=CC=C1)OC(C(F)(F)F)(C(F)(F)F)C1=CC=CC=C1
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H314
[Precautionary statements ]

P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
[Hazard Codes ]

C
[Risk Statements ]

34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 3261 8/PG 3
[WGK Germany ]

3
[F ]

10-21
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29309090
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Skin Corr. 1B
Hazard InformationBack Directory
[Chemical Properties]

IUPAC Name: [2-({diphenyl[(1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-yl)oxy]-λ?-sulfanyl}oxy)-1,1,1,3,3,3-hexafluoropropan-2-yl]benzene
[Uses]

Versatile dehydrating and oxidizing agent. For chemistry and references, see Aldrichimica Acta .
[Preparation]

Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur can be prepared by the reaction of the potassium salt of 1,1,1,3,3,3-hexafluoro-2-phenylisopropanol with diphenyl sulfide in the presence of chlorine in ether at -78 °C.
[storage]

avoid moisture; readily hydrolyzed; stable at rt; decomposes slowly at rt in solution.
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