| Identification | Back Directory | [Name]
(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS | [CAS]
325168-89-6 | [Synonyms]
(R)-XylPhanePHOS
(R)-Xylyl-PHANEPhos
(R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.24,7]hexadeca-hexaene
(R)-Xylyl-PHANEPhos, (R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.2.24,7]hexadeca-hexaene
(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS
(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, Min. 97% CTH-(R)-3,5-xylyl-PHANEPHOS | [Molecular Formula]
C48H50P2 | [MDL Number]
MFCD03840578 | [MOL File]
325168-89-6.mol | [Molecular Weight]
688.86 |
| Chemical Properties | Back Directory | [Melting point ]
234-238 °C | [Boiling point ]
785.2±60.0 °C(Predicted) | [form ]
Powder | [color ]
white | [Optical Rotation]
[α]22/D -61.0, c = 0.1 in ethanol | [InChIKey]
LYHOBZAADXPPNW-UHFFFAOYSA-N | [SMILES]
Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3cc4CCc5ccc(CCc3cc4)cc5P(c6cc(C)cc(C)c6)c7cc(C)cc(C)c7 |
| Questions And Answer | Back Directory | [Reaction]
- Chiral ligand employed in the enantioselective hydrogenation of various ketones.
- Chiral ligand employed in the enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.
- Chiral ligand employed in the enantioselective [2+2] cycloaddition of oxabicyclic alkenes with terminal alkynes.
- Chiral ligand employed in the gold-catalyzed enantioselective Cope rearrangement of achiral 1,5-dienes.
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