| Identification | Back Directory | [Name]
2-BENZYLOXYPHENYLMAGNESIUM BROMIDE, 1M & | [CAS]
328000-16-4 | [Synonyms]
2-BENZYLOXYPHENYLMAGNESIUM BROMIDE, 1M &
2-benzyloxyphenylmagnesium bromide solution
2-Benzyloxyphenylmagnesium bromide, 0.25M 2-MeTHF
2-Benzyloxyphenylmagnesium bromide, 1M solution in THF
2-Benzyloxyphenylmagnesium bromide solution 1.0 in THF
2-Benzyloxyphenylmagnesium bromide 0.5M solution in THF
2-Benzyloxyphenylmagnesium bromide solution 1.0 M in THF
2-BenzyloxyphenylMagnesiuM broMide, 1M solution in THF, AcroSeal | [Molecular Formula]
C13H11BrMgO | [MDL Number]
MFCD08705262 | [MOL File]
328000-16-4.mol |
| Chemical Properties | Back Directory | [density ]
1.047 g/mL at 25 °C | [Fp ]
-20 °C | [InChI]
1S/C13H11O.BrH.Mg/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13;;/h1-9H,11H2;1H;/q;;+1/p-1 | [InChIKey]
VELKJPFZDYXBDE-UHFFFAOYSA-M | [SMILES]
Br[Mg]c1ccccc1OCc2ccccc2 |
| Hazard Information | Back Directory | [Uses]
2-Benzyloxyphenylmagnesium bromide can be used:
- As a substrate in the iron-catalyzed coupling reaction of aryl Grignard reagents with unprotected bromophenols.
- As a substrate in the cross-coupling of Grignard reagents using diaryl titanates and ferric chloride.
- In one of the key synthetic steps for the total synthesis of an antibiotic caboxamycin.
| [reaction suitability]
reaction type: Grignard Reaction |
|
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