ChemicalBook--->CAS DataBase List--->32993-05-8

32993-05-8

32993-05-8 Structure

32993-05-8 Structure
IdentificationBack Directory
[Name]

Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
[CAS]

32993-05-8
[Synonyms]

[ClRu(PPh3)2Cp]
Cyclopentadienyl
bis(triphenylphosphane)
cyclopenta-2,4-dien-1-ide
λ2-chloranidylrutheniumbis(ylium)
chlorocyclopentadienylbis(triphenylphosphine)ruthenium
Chlorocyclopentadienylbis-(triphenylphosphino)-ruthenium
Bis(triphenylphosphine)(chloro)cyclopentadienylruthenium
Bis(triphenylphosphine)cyclopentadienylruthenium chloride
Cyclopentadienylbis(triphenylphosphine)ruthenium chloride
Chlorocyclopentadienylbis(triphenylphosphine)rutenium(II)
CHLOROCYCLOPENTADIENYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(Ⅱ)
Cyclopentadienylbis(triphenylphosphine)ruthenium(II) Chloride
Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),98%
Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(II),99%
Chlorocyclopentadienylbis(triphenylphosphine)rutheniuM(II), 98% 5GR
Chloro(cyclopentadienyl)bis(triphenylphosphine)rutheniuM(II),99% Cp(PPh3)2RuCl
[Molecular Formula]

C41H35ClP2Ru
[MDL Number]

MFCD00075004
[MOL File]

32993-05-8.mol
[Molecular Weight]

726.19
Chemical PropertiesBack Directory
[Appearance]

Orange powder
[Melting point ]

135 °C (dec.)(lit.)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

crystal
[color ]

orange
[Water Solubility ]

soluble
[Sensitive ]

Air & Moisture Sensitive
[InChI]

InChI=1S/2C18H15P.C5H5.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h2*1-15H;1-5H;1H;/q;;;;+1/p-1
[InChIKey]

YUYGUQQDGRTJMA-UHFFFAOYSA-M
[SMILES]

P(C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1=CC=CC=C1.[CH]1[CH][CH][CH][CH]1.Cl[Ru] |^1:38,39,40,41,42|
Hazard InformationBack Directory
[Chemical Properties]

Orange powder
[Uses]

Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride is used as an efficient transfer hydrogenation catalyst. It is used in the formation of indoles, isoquinolines and quinolines.
[reaction suitability]

core: ruthenium
reagent type: catalyst
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302+H312+H332-H315-H319-H335
[Precautionary statements ]

P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22-36/37/38
[Safety Statements ]

26-37/39-36/37/39-22
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

28439000
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Spectrum DetailBack Directory
[Spectrum Detail]

Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)(32993-05-8)1HNMR
Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)(32993-05-8)31PNMR
Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)(32993-05-8)IR
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