| Identification | Back Directory | [Name]
3-Furancarboxylicacid,5-methyl-,methylester(9CI) | [CAS]
35351-35-0 | [Synonyms]
Methyl 5-methyl-3-furoate
Methyl 5-methylfuran-3-carboxylate
5-Methyl-3-furancarboxylic acid methyl ester
3-Furancarboxylic acid, 5-methyl-, methyl ester
3-Furancarboxylicacid,5-methyl-,methylester(9CI) | [Molecular Formula]
C7H8O3 | [MDL Number]
MFCD11656598 | [MOL File]
35351-35-0.mol | [Molecular Weight]
140.14 |
| Chemical Properties | Back Directory | [Boiling point ]
80-83 °C(Press: 29 Torr) | [density ]
1.108±0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [Appearance]
Colorless to light yellow Liquid |
| Hazard Information | Back Directory | [Synthesis]
Palladium(II) acetate [Pd(OAc)2] (0.2 mmol), H4PMo11V1O40 (15 μmol), cerium chloride heptahydrate (CeCl3-7H2O) (0.2 mmol), methanol (30 mmol), and acetic acid (4.5 mL) were added sequentially to the reactor. The reaction mixture was heated to 70 °C. A mixture of methyl acrylate (1 mmol), propionaldehyde (6 mmol) and acetic acid (0.5 mL) was added dropwise to the reaction system using a syringe pump at a rate of 5 μL/min under an oxygen atmosphere of 1 atm (0.1 MPa) for 8 hours. Upon completion of the reaction, the reaction mixture was analyzed by gas chromatography and the yield of methyl 5-methyl-3-furancarboxylate was measured to be 90%. | [References]
[1] Journal of Organic Chemistry, 2007, vol. 72, # 23, p. 8820 - 8823
[2] Patent: US2007/197806, 2007, A1. Location in patent: Page/Page column 7 |
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SynAsst Chemical.
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021-60343070 |
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Modachem Shanghai Co., Ltd
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