ChemicalBook--->CAS DataBase List--->3547-33-9

3547-33-9

3547-33-9 Structure

3547-33-9 Structure
IdentificationBack Directory
[Name]

2-HYDROXYETHYL-N-OCTYL SULPHIDE
[CAS]

3547-33-9
[Synonyms]

R-874
MGK 874
Repellent 874
r-874phillips
r-874 Phillips
mgkrepellent874
mgkrepellentr-874
MGK Repellent 874
PHILLIPS R-874(R)
MGK repellent R-874
2-(octylthio)-ethano
2-(Oktylthio)ethanol
MGK REPELLENT 874(R)
2-(OCTYLTHIO)ETHANOL
Ethanol, 2-(octylthio)-
2-Oxyethyloctylsulfphide
2-(OCTYLSULFANYL)ETHANOL
HYDROXYETHYLOCTYLSULPHIDE
2-HYDROXYETHYLOCTYLSULFIDE
2-(Octylsulfanyl)ethan-1-ol
2-Hydroxyethyl-n-octyl-sulde
N-OCTYL-2-HYDROXYETHYLSULFIDE
2-hydroxyethyl-n-octylsulfide
2-Hydroxyethyl n-octyl sulfide
B-HYDROXYETHYL N-OCTYL SULFIDE
2-HYDROXYETHYL-N-OCTYL SULPHIDE
BETA-HYDROXYETHYL N-OCTYL SULFIDE
2-HYDROXYETHYL-N-OCTYL SULPHIDE, 1GM, NE AT
2-(octylthio)ethanol 2-hydroxyethyl octyl sulphide
2-hydroxyethyln-octylsulfide(plusrelatedactivecompounds)
[EINECS(EC#)]

222-598-4
[Molecular Formula]

C10H22OS
[MDL Number]

MFCD00014046
[MOL File]

3547-33-9.mol
[Molecular Weight]

190.35
Chemical PropertiesBack Directory
[Melting point ]

0°C
[Boiling point ]

325.88°C (rough estimate)
[density ]

0.9300
[vapor pressure ]

0.042Pa at 25℃
[refractive index ]

1.4760 (estimate)
[storage temp. ]

-15°C
[pka]

14.52±0.10(Predicted)
[color ]

Pale-amber liquid
[BRN ]

1698968
[LogP]

3.64
[EPA Substance Registry System]

2-Hydroxyethyl octyl sulfide (3547-33-9)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

41
[Safety Statements ]

26
[RIDADR ]

UN 3082 9 / PGIII
[RTECS ]

KL9700000
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[Toxicity]

LD50 orl-rat: 8530 mg/kg FMCHA2 -,C157,83
Hazard InformationBack Directory
[Description]

2-(octylthio)ethanol is a largely obsolete volatile insect repellent that was mainly used to control termite infestations. Data regarding its environmental fate is scant. It is moderately toxic to fish, algae and aquatic invertebrates. It had a low mammalian oral toxicity and is a recognised skin and eye irritant.
[Definition]

ChEBI: 2-(Octylthio)ethanol is an organic sulfide.
[Production Methods]

The industrial manufacturing process for 2 (octylthio)ethanol is not available in open literature. However, it can be inferred from its structure. Industrial preparation would begin with formation of the octylthiolate intermediate, typically generated by reacting an octyl halide with a sulphide or thiolate source under controlled basic conditions. This nucleophilic sulphur species would then be reacted with ethylene oxide or 2 chloroethanol to introduce the hydroxyethyl group, forming the thioether linkage characteristic of 2 (octylthio)ethanol. After condensation, the crude product would be purified through washing and fractional distillation to achieve the purity required for use in repellent formulations.
[Mechanism of action]

Repellent
[Safety Profile]

Mildly toxic by ingestion and skincontact. An insect repellent. When heated todecomposition it emits toxic fumes of SOx.
[Pesticide Type]

Insecticide; Semiochemical
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