| Identification | Back Directory | [Name]
(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) | [CAS]
361346-80-7 | [Synonyms]
(R)-AMAC
(R,R)-AMAC
(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
(E)-3-[[(1R,2R)-2-[[(E)-2-acetyl-3-oxidobut-2-enylidene]amino]-1,2-bis(2,4,6-trimethylphenyl)ethyl]iminomethyl]-4-oxopent-2-en-2-olate | [Molecular Formula]
C32H38CoN2O4 | [MDL Number]
MFCD06797061 | [MOL File]
361346-80-7.mol | [Molecular Weight]
573.59 |
| Chemical Properties | Back Directory | [Melting point ]
246-250°C | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
solid | [Optical Rotation]
[α]/D 291°, c = 0.1 in chloroform | [InChIKey]
PHCQQLMRNZRDJA-ZQBGJXBSSA-L | [SMILES]
CC(=O)C1=C(C)O[Co]OC(C)=C(\C=N\[C@@H]([C@H](\N=C\1)c2c(C)cc(C)cc2C)c3c(C)cc(C)cc3C)C(C)=O |
| Hazard Information | Back Directory | [Uses]
- Schiff base-cobalt complex catalyst for asymmetric borohydride reduction of carbonyl compounds
Catalyst for:
- Enantioselective borohydride reduction
- Stereoselective preparation of aryl alcohols via asymmetric reduction of aryl ketones with borohydride
- Stereoselective borohydride reduction of diketones to diols
- Stereoselective preparation of optically active deuterated primary alcohols via enantioselective borodeuteride reduction of aldehydes
- Stereoselective preparation of β-hydroxy esters via dynamic kinetic resolution of alkylketo esters with enantioselective borohydride reduction
- Chemoselective, diastereoselective, and enantioselective borohydride reduction of 1,3-diketones
- Asymmetric synthesis of diarylhydroxypropanones by stereoselective reduction of alkyldiaryldiketones
|
|
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Maya High Purity Chemicals
|
| Tel: |
+86 (573) 82222445 (0)18006601000 452520369 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm |
| Company Name: |
TCI Europe
|
| Tel: |
320-37350700 |
| Website: |
https://www.tcichemicals.com/de/de/index.html |
| Company Name: |
TCI AMERICA
|
| Tel: |
800-4238616 |
| Website: |
https://www.tcichemicals.com/en/us/index.html |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Alfa Chemistry
|
| Tel: |
1-516-6625404 |
| Website: |
https://www.alfa-chemistry.com |
|