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37095-27-5

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37095-27-5 Structure

37095-27-5 Structure
IdentificationBack Directory
[Name]

[mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99%
[CAS]

37095-27-5
[Synonyms]

(DPPM)(AuCl)2
Methylenebis[diphenyl]phosphine gold complex
Bis(chlorogold) bis(diphenylphosphino)methane
[mu-Bis(diphenylphosphino)methane]dichlorodigold
(mu-Bis(diphenylphosphino)methane)bis(chlorogold)
[Mu-Bis(diphenylphosphino)Methane]dichlorodigold(III)
[μ-Bis(diphenylphosphino)methane]dichlorodigold(I),98%
[Mu-Bis(diphenylphosphino)Methane]dichlorodigold(I),99%
[mu-Bis(diphenylphosphino)methane]dichlorodigold(I), 99%
[μ-Bis(diphenylphosphino) methane]dichlorodigold(I), 99%
[mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99%
[μ-Bis(diphenylphosphino)Methane]dichlorodigold(I),98% (DPPM)(AuCl)2
[Molecular Formula]

C25H22P2.2AuCl
[MDL Number]

MFCD08705280
[MOL File]

37095-27-5.mol
[Molecular Weight]

849.243
Chemical PropertiesBack Directory
[Melting point ]

271-272℃
[form ]

Powder
[color ]

white
[InChI]

InChI=1S/C25H22P2.2Au.2ClH/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25;;;;/h1-20H,21H2;;;2*1H/q;2*+1;;/p-2
[InChIKey]

JNPUWTQJFLJEJC-UHFFFAOYSA-L
[SMILES]

[Au]Cl.[Au]Cl.P(CP(C1C=CC=CC=1)C1C=CC=CC=1)(C1C=CC=CC=1)C1=CC=CC=C1
Safety DataBack Directory
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reactions]

  1. Catalyst used with chiral counter-ion for asymmetric hydroalkoxylation.
  2. Catalyst used for intramolecular acetylene Schmidt reaction.
Reactions of 37095-27-5
Hazard InformationBack Directory
[Uses]

Used for
  • Pharmacological studies involving the anticancer activity of gold(I)-phosphine complexes as autophagy-inducing agents
  • Triplet luminescent light emitting diodes with low turn-on voltage

Catalyst for:
  • Stereoselective preparation of vinyltetrahydrofuran via intramolecular hydroalkoxylation
  • Hydroamination and hydroalkoxylation reactions
  • Asymmetric transition metal catalysis
  • Gold(I) catalyzed intramolecular Schmidt reactions of homopropargyl azides
[reaction suitability]

core: gold
reagent type: catalyst
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